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Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridocuprate(II)
In the crystal structure of the title salt, (C(5)H(9)N(2))(2)[CuCl(4)], the organic cations and the tetrahedral [CuCl(4)] anions are linked into a three-dimensional network by N—H⋯Cl hydrogen bonds. The two 2-ethyl imidazolium cations in the asymmetric unit differ in the orientation of the ethyl gro...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050348/ https://www.ncbi.nlm.nih.gov/pubmed/21522525 http://dx.doi.org/10.1107/S160053681005261X |
| _version_ | 1782199343059566592 |
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| author | Zhu, Run-Qiang |
| author_facet | Zhu, Run-Qiang |
| author_sort | Zhu, Run-Qiang |
| collection | PubMed |
| description | In the crystal structure of the title salt, (C(5)H(9)N(2))(2)[CuCl(4)], the organic cations and the tetrahedral [CuCl(4)] anions are linked into a three-dimensional network by N—H⋯Cl hydrogen bonds. The two 2-ethyl imidazolium cations in the asymmetric unit differ in the orientation of the ethyl group, with N—C—C—C torsion angles of −170.0 (4) and −87.6 (5)°. |
| format | Text |
| id | pubmed-3050348 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30503482011-04-26 Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridocuprate(II) Zhu, Run-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title salt, (C(5)H(9)N(2))(2)[CuCl(4)], the organic cations and the tetrahedral [CuCl(4)] anions are linked into a three-dimensional network by N—H⋯Cl hydrogen bonds. The two 2-ethyl imidazolium cations in the asymmetric unit differ in the orientation of the ethyl group, with N—C—C—C torsion angles of −170.0 (4) and −87.6 (5)°. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050348/ /pubmed/21522525 http://dx.doi.org/10.1107/S160053681005261X Text en © Run-Qiang Zhu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhu, Run-Qiang Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridocuprate(II) |
| title | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridocuprate(II) |
| title_full | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridocuprate(II) |
| title_fullStr | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridocuprate(II) |
| title_full_unstemmed | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridocuprate(II) |
| title_short | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridocuprate(II) |
| title_sort | bis(2-ethyl-1h-imidazol-3-ium) tetrachloridocuprate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050348/ https://www.ncbi.nlm.nih.gov/pubmed/21522525 http://dx.doi.org/10.1107/S160053681005261X |
| work_keys_str_mv | AT zhurunqiang bis2ethyl1himidazol3iumtetrachloridocuprateii |