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Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) ethane-1,2-diol monosolvate

The title compound, [Co(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), has the Co(2+) ion in a distorted octa­hedral CoN(4)O(2) coordination geometry. A twofold rotation axis passes through the Co and S atoms, and through the mid-point of the C—C bond of the ethane­diol mol­ecule. In the crystal, the [CoSO...

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Detalles Bibliográficos
Autores principales: Zhong, Kai-Long, Pan, Xian-Xiao, Cao, Guo-Qing, Chen, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050350/
https://www.ncbi.nlm.nih.gov/pubmed/21522564
http://dx.doi.org/10.1107/S1600536810050592
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author Zhong, Kai-Long
Pan, Xian-Xiao
Cao, Guo-Qing
Chen, Lin
author_facet Zhong, Kai-Long
Pan, Xian-Xiao
Cao, Guo-Qing
Chen, Lin
author_sort Zhong, Kai-Long
collection PubMed
description The title compound, [Co(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), has the Co(2+) ion in a distorted octa­hedral CoN(4)O(2) coordination geometry. A twofold rotation axis passes through the Co and S atoms, and through the mid-point of the C—C bond of the ethane­diol mol­ecule. In the crystal, the [CoSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are held together by a pair of O—H⋯O hydrogen bonds.
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spelling pubmed-30503502011-04-26 Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) ethane-1,2-diol monosolvate Zhong, Kai-Long Pan, Xian-Xiao Cao, Guo-Qing Chen, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), has the Co(2+) ion in a distorted octa­hedral CoN(4)O(2) coordination geometry. A twofold rotation axis passes through the Co and S atoms, and through the mid-point of the C—C bond of the ethane­diol mol­ecule. In the crystal, the [CoSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are held together by a pair of O—H⋯O hydrogen bonds. International Union of Crystallography 2010-12-08 /pmc/articles/PMC3050350/ /pubmed/21522564 http://dx.doi.org/10.1107/S1600536810050592 Text en © Zhong et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhong, Kai-Long
Pan, Xian-Xiao
Cao, Guo-Qing
Chen, Lin
Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) ethane-1,2-diol monosolvate
title Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) ethane-1,2-diol monosolvate
title_full Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) ethane-1,2-diol monosolvate
title_fullStr Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) ethane-1,2-diol monosolvate
title_full_unstemmed Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) ethane-1,2-diol monosolvate
title_short Bis(2,2′-bipyridyl-κ(2) N,N′)(sulfato-κ(2) O,O′)cobalt(II) ethane-1,2-diol monosolvate
title_sort bis(2,2′-bipyridyl-κ(2) n,n′)(sulfato-κ(2) o,o′)cobalt(ii) ethane-1,2-diol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050350/
https://www.ncbi.nlm.nih.gov/pubmed/21522564
http://dx.doi.org/10.1107/S1600536810050592
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