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[(1,2,5,6-η)-Cycloocta-1,5-diene]bis(4-methylphenyl)platinum(II)
In the mononuclear title complex, [Pt(C(7)H(7))(2)(C(8)H(12))], the Pt(II) ion exhibits a square-planar coordination geometry defined by two methylphenyl ligands and the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene. The two methylphenyl groups have a cis relationship wi...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050351/ https://www.ncbi.nlm.nih.gov/pubmed/21522559 http://dx.doi.org/10.1107/S1600536810049664 |
Sumario: | In the mononuclear title complex, [Pt(C(7)H(7))(2)(C(8)H(12))], the Pt(II) ion exhibits a square-planar coordination geometry defined by two methylphenyl ligands and the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene. The two methylphenyl groups have a cis relationship with a C—Pt—C bond angle of 88.54 (18)° and a dihedral angle between the mean planes of the benzene rings of 83.87 (1)°. Each complex molecule links to four symmetry-related ones through intermolecular C—H⋯π interactions, forming a layer almost parallel to the bc plane. |
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