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[(1,2,5,6-η)-Cycloocta-1,5-diene]bis(4-methylphenyl)platinum(II)
In the mononuclear title complex, [Pt(C(7)H(7))(2)(C(8)H(12))], the Pt(II) ion exhibits a square-planar coordination geometry defined by two methylphenyl ligands and the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene. The two methylphenyl groups have a cis relationship wi...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050351/ https://www.ncbi.nlm.nih.gov/pubmed/21522559 http://dx.doi.org/10.1107/S1600536810049664 |
| _version_ | 1782199343758966784 |
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| author | Wang, Zhi-Wei Liu, Ran Liu, Hong-Yu Wan, Chong-Qing |
| author_facet | Wang, Zhi-Wei Liu, Ran Liu, Hong-Yu Wan, Chong-Qing |
| author_sort | Wang, Zhi-Wei |
| collection | PubMed |
| description | In the mononuclear title complex, [Pt(C(7)H(7))(2)(C(8)H(12))], the Pt(II) ion exhibits a square-planar coordination geometry defined by two methylphenyl ligands and the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene. The two methylphenyl groups have a cis relationship with a C—Pt—C bond angle of 88.54 (18)° and a dihedral angle between the mean planes of the benzene rings of 83.87 (1)°. Each complex molecule links to four symmetry-related ones through intermolecular C—H⋯π interactions, forming a layer almost parallel to the bc plane. |
| format | Text |
| id | pubmed-3050351 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30503512011-04-26 [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(4-methylphenyl)platinum(II) Wang, Zhi-Wei Liu, Ran Liu, Hong-Yu Wan, Chong-Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Pt(C(7)H(7))(2)(C(8)H(12))], the Pt(II) ion exhibits a square-planar coordination geometry defined by two methylphenyl ligands and the mid-points of the two π-coordinated double bonds of cycloocta-1,5-diene. The two methylphenyl groups have a cis relationship with a C—Pt—C bond angle of 88.54 (18)° and a dihedral angle between the mean planes of the benzene rings of 83.87 (1)°. Each complex molecule links to four symmetry-related ones through intermolecular C—H⋯π interactions, forming a layer almost parallel to the bc plane. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050351/ /pubmed/21522559 http://dx.doi.org/10.1107/S1600536810049664 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Zhi-Wei Liu, Ran Liu, Hong-Yu Wan, Chong-Qing [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(4-methylphenyl)platinum(II) |
| title | [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(4-methylphenyl)platinum(II) |
| title_full | [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(4-methylphenyl)platinum(II) |
| title_fullStr | [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(4-methylphenyl)platinum(II) |
| title_full_unstemmed | [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(4-methylphenyl)platinum(II) |
| title_short | [(1,2,5,6-η)-Cycloocta-1,5-diene]bis(4-methylphenyl)platinum(II) |
| title_sort | [(1,2,5,6-η)-cycloocta-1,5-diene]bis(4-methylphenyl)platinum(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050351/ https://www.ncbi.nlm.nih.gov/pubmed/21522559 http://dx.doi.org/10.1107/S1600536810049664 |
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