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(1E,4E)-1,5-Bis(2,4,6-trimethoxyphenyl)penta-1,4-dien-3-one
There are two crystallographically independent molecules in the asymmetric unit of the title bischalcone derivative, C(23)H(26)O(7). The molecules are unsymmetrical and almost planar: the dihedral angle between two benzene rings is 1.04 (7)° in one molecule and 2.31 (7)° in the other. The centra...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050352/ https://www.ncbi.nlm.nih.gov/pubmed/21522745 http://dx.doi.org/10.1107/S1600536810049299 |
Sumario: | There are two crystallographically independent molecules in the asymmetric unit of the title bischalcone derivative, C(23)H(26)O(7). The molecules are unsymmetrical and almost planar: the dihedral angle between two benzene rings is 1.04 (7)° in one molecule and 2.31 (7)° in the other. The central penta-1,4-dien-3-one fragment makes dihedral angles of 7.61 (7) and 6.82 (7)° with the two adjacent benzene rings in one molecule, while the corresponding values are 7.85 (7) and 9.42 (6)° in the other. In both molecules, the three methoxy groups of the two 2,4,6-trimethoxyphenyl units are coplanar with the attached benzene rings [C—O—C—C- torsion angles of −1.5 (2), −7.2 (2) and 4.1 (2)° in one molecule and −0.7 (2), −5.5 (2) and −0.6 (2)° in the other]. The molecular conformations are stabilized by weak intramolecular C—H⋯O interactions generating two S(6) ring motifs. In the crystal, molecules are linked by weak intermolecular C—H⋯O interactions into zigzag chains parallel to the c axis. The crystal structure is further stabilized by C—H⋯π interactions and π–π interactions with centroid–centroid distances of 3.6433 (8) Å. |
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