{2-[(Benzo­yloxy)meth­yl]-1-oxo-3H-pyrrolizin-2-yl}methyl benzoate

The title compound, C(23)H(19)NO(5), was prepared by esterification of 2,2-bis­(hy­droxy­meth­yl)-2,3-dihydro-1H-pyrrolizin-1-one with benzoyl chloride in pyridine·The pyrrolizine ring system is approximately planar with a maximum deviation of 0.008 (2) Å from the least-squares plane; the two phenyl...

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Detalles Bibliográficos
Autores principales: Ali, Yousaf, Yousuf, Sammer, Afza, Nighat, Peng, Yu, Kalhoro, Mahboob Ali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050358/
https://www.ncbi.nlm.nih.gov/pubmed/21522679
http://dx.doi.org/10.1107/S1600536810051974
Descripción
Sumario:The title compound, C(23)H(19)NO(5), was prepared by esterification of 2,2-bis­(hy­droxy­meth­yl)-2,3-dihydro-1H-pyrrolizin-1-one with benzoyl chloride in pyridine·The pyrrolizine ring system is approximately planar with a maximum deviation of 0.008 (2) Å from the least-squares plane; the two phenyl rings are oriented at dihedral angles of 64.26 (11) and 70.75 (10)° with respect to the pyrrolizine ring system. Weak inter­molecular C—H⋯O hydrogen bonding occurs in the crystal structure.

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