{2-[(Benzo­yloxy)meth­yl]-1-oxo-3H-pyrrolizin-2-yl}methyl benzoate

The title compound, C(23)H(19)NO(5), was prepared by esterification of 2,2-bis­(hy­droxy­meth­yl)-2,3-dihydro-1H-pyrrolizin-1-one with benzoyl chloride in pyridine·The pyrrolizine ring system is approximately planar with a maximum deviation of 0.008 (2) Å from the least-squares plane; the two phenyl...

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Detalles Bibliográficos
Autores principales: Ali, Yousaf, Yousuf, Sammer, Afza, Nighat, Peng, Yu, Kalhoro, Mahboob Ali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050358/
https://www.ncbi.nlm.nih.gov/pubmed/21522679
http://dx.doi.org/10.1107/S1600536810051974
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author Ali, Yousaf
Yousuf, Sammer
Afza, Nighat
Peng, Yu
Kalhoro, Mahboob Ali
author_facet Ali, Yousaf
Yousuf, Sammer
Afza, Nighat
Peng, Yu
Kalhoro, Mahboob Ali
author_sort Ali, Yousaf
collection PubMed
description The title compound, C(23)H(19)NO(5), was prepared by esterification of 2,2-bis­(hy­droxy­meth­yl)-2,3-dihydro-1H-pyrrolizin-1-one with benzoyl chloride in pyridine·The pyrrolizine ring system is approximately planar with a maximum deviation of 0.008 (2) Å from the least-squares plane; the two phenyl rings are oriented at dihedral angles of 64.26 (11) and 70.75 (10)° with respect to the pyrrolizine ring system. Weak inter­molecular C—H⋯O hydrogen bonding occurs in the crystal structure.
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spelling pubmed-30503582011-04-26 {2-[(Benzo­yloxy)meth­yl]-1-oxo-3H-pyrrolizin-2-yl}methyl benzoate Ali, Yousaf Yousuf, Sammer Afza, Nighat Peng, Yu Kalhoro, Mahboob Ali Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(23)H(19)NO(5), was prepared by esterification of 2,2-bis­(hy­droxy­meth­yl)-2,3-dihydro-1H-pyrrolizin-1-one with benzoyl chloride in pyridine·The pyrrolizine ring system is approximately planar with a maximum deviation of 0.008 (2) Å from the least-squares plane; the two phenyl rings are oriented at dihedral angles of 64.26 (11) and 70.75 (10)° with respect to the pyrrolizine ring system. Weak inter­molecular C—H⋯O hydrogen bonding occurs in the crystal structure. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050358/ /pubmed/21522679 http://dx.doi.org/10.1107/S1600536810051974 Text en © Ali et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ali, Yousaf
Yousuf, Sammer
Afza, Nighat
Peng, Yu
Kalhoro, Mahboob Ali
{2-[(Benzo­yloxy)meth­yl]-1-oxo-3H-pyrrolizin-2-yl}methyl benzoate
title {2-[(Benzo­yloxy)meth­yl]-1-oxo-3H-pyrrolizin-2-yl}methyl benzoate
title_full {2-[(Benzo­yloxy)meth­yl]-1-oxo-3H-pyrrolizin-2-yl}methyl benzoate
title_fullStr {2-[(Benzo­yloxy)meth­yl]-1-oxo-3H-pyrrolizin-2-yl}methyl benzoate
title_full_unstemmed {2-[(Benzo­yloxy)meth­yl]-1-oxo-3H-pyrrolizin-2-yl}methyl benzoate
title_short {2-[(Benzo­yloxy)meth­yl]-1-oxo-3H-pyrrolizin-2-yl}methyl benzoate
title_sort {2-[(benzo­yloxy)meth­yl]-1-oxo-3h-pyrrolizin-2-yl}methyl benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050358/
https://www.ncbi.nlm.nih.gov/pubmed/21522679
http://dx.doi.org/10.1107/S1600536810051974
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