trans-Bis(dimethyl sulfoxide-κO)bis­(thio­semicarbazide-κ(2) N (1),S)cadmium dipicrate dihydrate

In the cation of the title compound, [Cd(CH(5)N(3)S)(2)(C(2)H(6)OS)(2)](C(6)H(2)N(3)O(7))(2)·2H(2)O, the Cd(II) atom is located on an inversion center. It is hexa­coordinated in an octahedral fashion by two thio­semicarbazide mol­ecules, which coordinate in a bidentate manner via the S and N atoms,...

Descripción completa

Detalles Bibliográficos
Autores principales: Shanthakumari, R., Hema, R., Ramamurthy, K., Stoeckli-Evans, Helen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050361/
https://www.ncbi.nlm.nih.gov/pubmed/21522538
http://dx.doi.org/10.1107/S1600536810053602
_version_ 1782199346128748544
author Shanthakumari, R.
Hema, R.
Ramamurthy, K.
Stoeckli-Evans, Helen
author_facet Shanthakumari, R.
Hema, R.
Ramamurthy, K.
Stoeckli-Evans, Helen
author_sort Shanthakumari, R.
collection PubMed
description In the cation of the title compound, [Cd(CH(5)N(3)S)(2)(C(2)H(6)OS)(2)](C(6)H(2)N(3)O(7))(2)·2H(2)O, the Cd(II) atom is located on an inversion center. It is hexa­coordinated in an octahedral fashion by two thio­semicarbazide mol­ecules, which coordinate in a bidentate manner via the S and N atoms, and to the O atom of two dimethyl sufoxide (DMSO) mol­ecules. The charges are equilibrated by two picrate anions and the complex crystallizes as a dihydrate. In the crystal, these units are linked by a number of O—H⋯O and N—H⋯S hydrogen bonds and weak C—H⋯O inter­actions, forming a three-dimensional network.
format Text
id pubmed-3050361
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30503612011-04-26 trans-Bis(dimethyl sulfoxide-κO)bis­(thio­semicarbazide-κ(2) N (1),S)cadmium dipicrate dihydrate Shanthakumari, R. Hema, R. Ramamurthy, K. Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [Cd(CH(5)N(3)S)(2)(C(2)H(6)OS)(2)](C(6)H(2)N(3)O(7))(2)·2H(2)O, the Cd(II) atom is located on an inversion center. It is hexa­coordinated in an octahedral fashion by two thio­semicarbazide mol­ecules, which coordinate in a bidentate manner via the S and N atoms, and to the O atom of two dimethyl sufoxide (DMSO) mol­ecules. The charges are equilibrated by two picrate anions and the complex crystallizes as a dihydrate. In the crystal, these units are linked by a number of O—H⋯O and N—H⋯S hydrogen bonds and weak C—H⋯O inter­actions, forming a three-dimensional network. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050361/ /pubmed/21522538 http://dx.doi.org/10.1107/S1600536810053602 Text en © Shanthakumari et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shanthakumari, R.
Hema, R.
Ramamurthy, K.
Stoeckli-Evans, Helen
trans-Bis(dimethyl sulfoxide-κO)bis­(thio­semicarbazide-κ(2) N (1),S)cadmium dipicrate dihydrate
title trans-Bis(dimethyl sulfoxide-κO)bis­(thio­semicarbazide-κ(2) N (1),S)cadmium dipicrate dihydrate
title_full trans-Bis(dimethyl sulfoxide-κO)bis­(thio­semicarbazide-κ(2) N (1),S)cadmium dipicrate dihydrate
title_fullStr trans-Bis(dimethyl sulfoxide-κO)bis­(thio­semicarbazide-κ(2) N (1),S)cadmium dipicrate dihydrate
title_full_unstemmed trans-Bis(dimethyl sulfoxide-κO)bis­(thio­semicarbazide-κ(2) N (1),S)cadmium dipicrate dihydrate
title_short trans-Bis(dimethyl sulfoxide-κO)bis­(thio­semicarbazide-κ(2) N (1),S)cadmium dipicrate dihydrate
title_sort trans-bis(dimethyl sulfoxide-κo)bis­(thio­semicarbazide-κ(2) n (1),s)cadmium dipicrate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050361/
https://www.ncbi.nlm.nih.gov/pubmed/21522538
http://dx.doi.org/10.1107/S1600536810053602
work_keys_str_mv AT shanthakumarir transbisdimethylsulfoxidekobisthiosemicarbazidek2n1scadmiumdipicratedihydrate
AT hemar transbisdimethylsulfoxidekobisthiosemicarbazidek2n1scadmiumdipicratedihydrate
AT ramamurthyk transbisdimethylsulfoxidekobisthiosemicarbazidek2n1scadmiumdipicratedihydrate
AT stoecklievanshelen transbisdimethylsulfoxidekobisthiosemicarbazidek2n1scadmiumdipicratedihydrate

Ejemplares similares