N-(2,5-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide

In the title compound, C(13)H(11)Cl(2)NO(2)S, the N—C bond in the C—SO(2)—NH—C segment has gauche torsion angles with respect to the S=O bonds. The mol­ecule is bent at the S atom with an C—SO(2)—NH—C torsion angle of 62.1 (2)°. Furthermore, the conformation of the N—H bond is syn to the ortho-chlor...

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Detalles Bibliográficos
Autores principales: Shakuntala, K., Foro, Sabine, Gowda, B. Thimme
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050363/
https://www.ncbi.nlm.nih.gov/pubmed/21522749
http://dx.doi.org/10.1107/S1600536810050270
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author Shakuntala, K.
Foro, Sabine
Gowda, B. Thimme
author_facet Shakuntala, K.
Foro, Sabine
Gowda, B. Thimme
author_sort Shakuntala, K.
collection PubMed
description In the title compound, C(13)H(11)Cl(2)NO(2)S, the N—C bond in the C—SO(2)—NH—C segment has gauche torsion angles with respect to the S=O bonds. The mol­ecule is bent at the S atom with an C—SO(2)—NH—C torsion angle of 62.1 (2)°. Furthermore, the conformation of the N—H bond is syn to the ortho-chloro group in the adjacent benzene ring. The benzene rings are tilted by 67.8 (1)° relative to each other. The crystal structure features dimers linked by N—H⋯O hydrogen bonds. An intra­molecular N—H⋯Cl hydrogen bond is also observed.
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spelling pubmed-30503632011-04-26 N-(2,5-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide Shakuntala, K. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(11)Cl(2)NO(2)S, the N—C bond in the C—SO(2)—NH—C segment has gauche torsion angles with respect to the S=O bonds. The mol­ecule is bent at the S atom with an C—SO(2)—NH—C torsion angle of 62.1 (2)°. Furthermore, the conformation of the N—H bond is syn to the ortho-chloro group in the adjacent benzene ring. The benzene rings are tilted by 67.8 (1)° relative to each other. The crystal structure features dimers linked by N—H⋯O hydrogen bonds. An intra­molecular N—H⋯Cl hydrogen bond is also observed. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050363/ /pubmed/21522749 http://dx.doi.org/10.1107/S1600536810050270 Text en © Shakuntala et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shakuntala, K.
Foro, Sabine
Gowda, B. Thimme
N-(2,5-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide
title N-(2,5-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide
title_full N-(2,5-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide
title_fullStr N-(2,5-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide
title_full_unstemmed N-(2,5-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide
title_short N-(2,5-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide
title_sort n-(2,5-dichloro­phen­yl)-4-methyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050363/
https://www.ncbi.nlm.nih.gov/pubmed/21522749
http://dx.doi.org/10.1107/S1600536810050270
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