Tetra­ethyl­ammonium (acetyl­acetonato)bromidotricarbonyl­rhenate(I)

In the title compound, (C(8)H(20)N)[ReBr(C(5)H(7)O(2))(CO)(3)], the Re(I) atom in the rhenate anion is surrounded by three carbonyl ligands orientated in a facial arrangement, a bromide ligand and an acetyl­acetonate ligand, leading to a distorted octa­hedral ReC(3)BrO(2) coordination with a O—Re—O...

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Detalles Bibliográficos
Autores principales: Brink, Alice, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050364/
https://www.ncbi.nlm.nih.gov/pubmed/21522557
http://dx.doi.org/10.1107/S1600536810050105
Descripción
Sumario:In the title compound, (C(8)H(20)N)[ReBr(C(5)H(7)O(2))(CO)(3)], the Re(I) atom in the rhenate anion is surrounded by three carbonyl ligands orientated in a facial arrangement, a bromide ligand and an acetyl­acetonate ligand, leading to a distorted octa­hedral ReC(3)BrO(2) coordination with a O—Re—O bite angle of 85.66 (7)°. An array of C—H⋯O and C—H⋯Br hydrogen-bonding inter­actions between the cations and the surrounding rhenate anions stabilize the crystal structure.

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