Tetra­ethyl­ammonium (acetyl­acetonato)bromidotricarbonyl­rhenate(I)

In the title compound, (C(8)H(20)N)[ReBr(C(5)H(7)O(2))(CO)(3)], the Re(I) atom in the rhenate anion is surrounded by three carbonyl ligands orientated in a facial arrangement, a bromide ligand and an acetyl­acetonate ligand, leading to a distorted octa­hedral ReC(3)BrO(2) coordination with a O—Re—O...

Descripción completa

Detalles Bibliográficos
Autores principales: Brink, Alice, Visser, Hendrik G., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050364/
https://www.ncbi.nlm.nih.gov/pubmed/21522557
http://dx.doi.org/10.1107/S1600536810050105
_version_ 1782199346825003008
author Brink, Alice
Visser, Hendrik G.
Roodt, Andreas
author_facet Brink, Alice
Visser, Hendrik G.
Roodt, Andreas
author_sort Brink, Alice
collection PubMed
description In the title compound, (C(8)H(20)N)[ReBr(C(5)H(7)O(2))(CO)(3)], the Re(I) atom in the rhenate anion is surrounded by three carbonyl ligands orientated in a facial arrangement, a bromide ligand and an acetyl­acetonate ligand, leading to a distorted octa­hedral ReC(3)BrO(2) coordination with a O—Re—O bite angle of 85.66 (7)°. An array of C—H⋯O and C—H⋯Br hydrogen-bonding inter­actions between the cations and the surrounding rhenate anions stabilize the crystal structure.
format Text
id pubmed-3050364
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30503642011-04-26 Tetra­ethyl­ammonium (acetyl­acetonato)bromidotricarbonyl­rhenate(I) Brink, Alice Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(8)H(20)N)[ReBr(C(5)H(7)O(2))(CO)(3)], the Re(I) atom in the rhenate anion is surrounded by three carbonyl ligands orientated in a facial arrangement, a bromide ligand and an acetyl­acetonate ligand, leading to a distorted octa­hedral ReC(3)BrO(2) coordination with a O—Re—O bite angle of 85.66 (7)°. An array of C—H⋯O and C—H⋯Br hydrogen-bonding inter­actions between the cations and the surrounding rhenate anions stabilize the crystal structure. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050364/ /pubmed/21522557 http://dx.doi.org/10.1107/S1600536810050105 Text en © Brink et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Brink, Alice
Visser, Hendrik G.
Roodt, Andreas
Tetra­ethyl­ammonium (acetyl­acetonato)bromidotricarbonyl­rhenate(I)
title Tetra­ethyl­ammonium (acetyl­acetonato)bromidotricarbonyl­rhenate(I)
title_full Tetra­ethyl­ammonium (acetyl­acetonato)bromidotricarbonyl­rhenate(I)
title_fullStr Tetra­ethyl­ammonium (acetyl­acetonato)bromidotricarbonyl­rhenate(I)
title_full_unstemmed Tetra­ethyl­ammonium (acetyl­acetonato)bromidotricarbonyl­rhenate(I)
title_short Tetra­ethyl­ammonium (acetyl­acetonato)bromidotricarbonyl­rhenate(I)
title_sort tetra­ethyl­ammonium (acetyl­acetonato)bromidotricarbonyl­rhenate(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050364/
https://www.ncbi.nlm.nih.gov/pubmed/21522557
http://dx.doi.org/10.1107/S1600536810050105
work_keys_str_mv AT brinkalice tetraethylammoniumacetylacetonatobromidotricarbonylrhenatei
AT visserhendrikg tetraethylammoniumacetylacetonatobromidotricarbonylrhenatei
AT roodtandreas tetraethylammoniumacetylacetonatobromidotricarbonylrhenatei

Ejemplares similares