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Bis{2-[3-(dimethyl­amino)­propyl­imino­meth­yl]-6-meth­oxy­phenolato}-κ(3) N,N′,O (1);κ(2) N,O (1)-zinc(II) dihydrate

In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal–bipyramidal environment. One O and two N atoms constitute the base of the p...

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Detalles Bibliográficos
Autores principales: Lin, Hong, Wang, Xiao-Juan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050366/
https://www.ncbi.nlm.nih.gov/pubmed/21522605
http://dx.doi.org/10.1107/S1600536810052438
Descripción
Sumario:In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal–bipyramidal environment. One O and two N atoms constitute the base of the pyramid, and one O and one N atoms occupy the apical positions. Inter­molecular O—H⋯O and O—H⋯N hydrogen bonds between the lattice water mol­ecules and N/O atoms of the Schiff base ligands stabilize the conformation, whereas inter­molecular O—H⋯O hydrogen bonds between the two lattice water mol­ecules lead to a chain structure in [001].