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Bis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato}-κ(3) N,N′,O (1);κ(2) N,O (1)-zinc(II) dihydrate
In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal–bipyramidal environment. One O and two N atoms constitute the base of the p...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050366/ https://www.ncbi.nlm.nih.gov/pubmed/21522605 http://dx.doi.org/10.1107/S1600536810052438 |
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author | Lin, Hong Wang, Xiao-Juan |
author_facet | Lin, Hong Wang, Xiao-Juan |
author_sort | Lin, Hong |
collection | PubMed |
description | In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal–bipyramidal environment. One O and two N atoms constitute the base of the pyramid, and one O and one N atoms occupy the apical positions. Intermolecular O—H⋯O and O—H⋯N hydrogen bonds between the lattice water molecules and N/O atoms of the Schiff base ligands stabilize the conformation, whereas intermolecular O—H⋯O hydrogen bonds between the two lattice water molecules lead to a chain structure in [001]. |
format | Text |
id | pubmed-3050366 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30503662011-04-26 Bis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato}-κ(3) N,N′,O (1);κ(2) N,O (1)-zinc(II) dihydrate Lin, Hong Wang, Xiao-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal–bipyramidal environment. One O and two N atoms constitute the base of the pyramid, and one O and one N atoms occupy the apical positions. Intermolecular O—H⋯O and O—H⋯N hydrogen bonds between the lattice water molecules and N/O atoms of the Schiff base ligands stabilize the conformation, whereas intermolecular O—H⋯O hydrogen bonds between the two lattice water molecules lead to a chain structure in [001]. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050366/ /pubmed/21522605 http://dx.doi.org/10.1107/S1600536810052438 Text en © Lin and Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lin, Hong Wang, Xiao-Juan Bis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato}-κ(3) N,N′,O (1);κ(2) N,O (1)-zinc(II) dihydrate |
title | Bis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato}-κ(3)
N,N′,O
(1);κ(2)
N,O
(1)-zinc(II) dihydrate |
title_full | Bis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato}-κ(3)
N,N′,O
(1);κ(2)
N,O
(1)-zinc(II) dihydrate |
title_fullStr | Bis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato}-κ(3)
N,N′,O
(1);κ(2)
N,O
(1)-zinc(II) dihydrate |
title_full_unstemmed | Bis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato}-κ(3)
N,N′,O
(1);κ(2)
N,O
(1)-zinc(II) dihydrate |
title_short | Bis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato}-κ(3)
N,N′,O
(1);κ(2)
N,O
(1)-zinc(II) dihydrate |
title_sort | bis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato}-κ(3)
n,n′,o
(1);κ(2)
n,o
(1)-zinc(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050366/ https://www.ncbi.nlm.nih.gov/pubmed/21522605 http://dx.doi.org/10.1107/S1600536810052438 |
work_keys_str_mv | AT linhong bis23dimethylaminopropyliminomethyl6methoxyphenolatok3nno1k2no1zinciidihydrate AT wangxiaojuan bis23dimethylaminopropyliminomethyl6methoxyphenolatok3nno1k2no1zinciidihydrate |