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Bis{2-[3-(dimethyl­amino)­propyl­imino­meth­yl]-6-meth­oxy­phenolato}-κ(3) N,N′,O (1);κ(2) N,O (1)-zinc(II) dihydrate

In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal–bipyramidal environment. One O and two N atoms constitute the base of the p...

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Detalles Bibliográficos
Autores principales: Lin, Hong, Wang, Xiao-Juan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050366/
https://www.ncbi.nlm.nih.gov/pubmed/21522605
http://dx.doi.org/10.1107/S1600536810052438
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author Lin, Hong
Wang, Xiao-Juan
author_facet Lin, Hong
Wang, Xiao-Juan
author_sort Lin, Hong
collection PubMed
description In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal–bipyramidal environment. One O and two N atoms constitute the base of the pyramid, and one O and one N atoms occupy the apical positions. Inter­molecular O—H⋯O and O—H⋯N hydrogen bonds between the lattice water mol­ecules and N/O atoms of the Schiff base ligands stabilize the conformation, whereas inter­molecular O—H⋯O hydrogen bonds between the two lattice water mol­ecules lead to a chain structure in [001].
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spelling pubmed-30503662011-04-26 Bis{2-[3-(dimethyl­amino)­propyl­imino­meth­yl]-6-meth­oxy­phenolato}-κ(3) N,N′,O (1);κ(2) N,O (1)-zinc(II) dihydrate Lin, Hong Wang, Xiao-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal–bipyramidal environment. One O and two N atoms constitute the base of the pyramid, and one O and one N atoms occupy the apical positions. Inter­molecular O—H⋯O and O—H⋯N hydrogen bonds between the lattice water mol­ecules and N/O atoms of the Schiff base ligands stabilize the conformation, whereas inter­molecular O—H⋯O hydrogen bonds between the two lattice water mol­ecules lead to a chain structure in [001]. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050366/ /pubmed/21522605 http://dx.doi.org/10.1107/S1600536810052438 Text en © Lin and Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lin, Hong
Wang, Xiao-Juan
Bis{2-[3-(dimethyl­amino)­propyl­imino­meth­yl]-6-meth­oxy­phenolato}-κ(3) N,N′,O (1);κ(2) N,O (1)-zinc(II) dihydrate
title Bis{2-[3-(dimethyl­amino)­propyl­imino­meth­yl]-6-meth­oxy­phenolato}-κ(3) N,N′,O (1);κ(2) N,O (1)-zinc(II) dihydrate
title_full Bis{2-[3-(dimethyl­amino)­propyl­imino­meth­yl]-6-meth­oxy­phenolato}-κ(3) N,N′,O (1);κ(2) N,O (1)-zinc(II) dihydrate
title_fullStr Bis{2-[3-(dimethyl­amino)­propyl­imino­meth­yl]-6-meth­oxy­phenolato}-κ(3) N,N′,O (1);κ(2) N,O (1)-zinc(II) dihydrate
title_full_unstemmed Bis{2-[3-(dimethyl­amino)­propyl­imino­meth­yl]-6-meth­oxy­phenolato}-κ(3) N,N′,O (1);κ(2) N,O (1)-zinc(II) dihydrate
title_short Bis{2-[3-(dimethyl­amino)­propyl­imino­meth­yl]-6-meth­oxy­phenolato}-κ(3) N,N′,O (1);κ(2) N,O (1)-zinc(II) dihydrate
title_sort bis{2-[3-(dimethyl­amino)­propyl­imino­meth­yl]-6-meth­oxy­phenolato}-κ(3) n,n′,o (1);κ(2) n,o (1)-zinc(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050366/
https://www.ncbi.nlm.nih.gov/pubmed/21522605
http://dx.doi.org/10.1107/S1600536810052438
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AT wangxiaojuan bis23dimethylaminopropyliminomethyl6methoxyphenolatok3nno1k2no1zinciidihydrate