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Dibromidobis(1-ethyl-2,6-dimethylpyridinium-4-olate-κO)zinc(II)
In the bioactive title compound, [ZnBr(2)(C(9)H(13)NO)(2)], the Zn(II) atom is coordinated in a distorted tetrahedral arrangement by two Br(−) anions and the O atoms of two zwitterionic organic ligands. The pyridinium rings are almost planar [maximum deviations = 0.004 (4) and 0.003 (4) Å]. The eth...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050368/ https://www.ncbi.nlm.nih.gov/pubmed/21522518 http://dx.doi.org/10.1107/S1600536810052190 |
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author | Thenmozhi, M. Philominal, A. Dhanuskodi, S. Ponnuswamy, M. N. |
author_facet | Thenmozhi, M. Philominal, A. Dhanuskodi, S. Ponnuswamy, M. N. |
author_sort | Thenmozhi, M. |
collection | PubMed |
description | In the bioactive title compound, [ZnBr(2)(C(9)H(13)NO)(2)], the Zn(II) atom is coordinated in a distorted tetrahedral arrangement by two Br(−) anions and the O atoms of two zwitterionic organic ligands. The pyridinium rings are almost planar [maximum deviations = 0.004 (4) and 0.003 (4) Å]. The ethyl groups are approximately perpendicular to the corresponding pyridinium ring planes [N—C—C—C = 88.8 (4)° in each ligand]. The packing of the molecules is controlled by π–π interactions, with centroid–centroid distances of 3.625 (3) and 3.711 (2) Å, forming chains approximately parallel to (102). The crystal studied was non-merohedrally twinned (twin relationship between the domains 1 0 0, 0 1 0, −0.4672 −0.1864 −1 and batch scale factor of 7.39%). |
format | Text |
id | pubmed-3050368 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30503682011-04-26 Dibromidobis(1-ethyl-2,6-dimethylpyridinium-4-olate-κO)zinc(II) Thenmozhi, M. Philominal, A. Dhanuskodi, S. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the bioactive title compound, [ZnBr(2)(C(9)H(13)NO)(2)], the Zn(II) atom is coordinated in a distorted tetrahedral arrangement by two Br(−) anions and the O atoms of two zwitterionic organic ligands. The pyridinium rings are almost planar [maximum deviations = 0.004 (4) and 0.003 (4) Å]. The ethyl groups are approximately perpendicular to the corresponding pyridinium ring planes [N—C—C—C = 88.8 (4)° in each ligand]. The packing of the molecules is controlled by π–π interactions, with centroid–centroid distances of 3.625 (3) and 3.711 (2) Å, forming chains approximately parallel to (102). The crystal studied was non-merohedrally twinned (twin relationship between the domains 1 0 0, 0 1 0, −0.4672 −0.1864 −1 and batch scale factor of 7.39%). International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050368/ /pubmed/21522518 http://dx.doi.org/10.1107/S1600536810052190 Text en © Thenmozhi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Thenmozhi, M. Philominal, A. Dhanuskodi, S. Ponnuswamy, M. N. Dibromidobis(1-ethyl-2,6-dimethylpyridinium-4-olate-κO)zinc(II) |
title | Dibromidobis(1-ethyl-2,6-dimethylpyridinium-4-olate-κO)zinc(II) |
title_full | Dibromidobis(1-ethyl-2,6-dimethylpyridinium-4-olate-κO)zinc(II) |
title_fullStr | Dibromidobis(1-ethyl-2,6-dimethylpyridinium-4-olate-κO)zinc(II) |
title_full_unstemmed | Dibromidobis(1-ethyl-2,6-dimethylpyridinium-4-olate-κO)zinc(II) |
title_short | Dibromidobis(1-ethyl-2,6-dimethylpyridinium-4-olate-κO)zinc(II) |
title_sort | dibromidobis(1-ethyl-2,6-dimethylpyridinium-4-olate-κo)zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050368/ https://www.ncbi.nlm.nih.gov/pubmed/21522518 http://dx.doi.org/10.1107/S1600536810052190 |
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