catena-Poly[[[aqua­(pyridine-4-carboxyl­ato-κN)silver(I)]-μ-hexa­methyl­ene­tetra­amine-κ(2) N:N′] dihydrate]

In the title compound, {[Ag(C(6)H(4)NO(2))(C(6)H(12)N(4))(H(2)O)]·2H(2)O}(n), the Ag(I) atom shows a distorted triangular pyramidal geometry,, formed by two N atoms from two hexa­methyl­ene­tetra­amine (hmt) ligands and one N atom from a pyridine-4-carboxyl­ate (4-pdc) ligand and one water mol­ecule...

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Detalles Bibliográficos
Autores principales: Sun, Dajun, Han, Liying, Zang, Hu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050371/
https://www.ncbi.nlm.nih.gov/pubmed/21522567
http://dx.doi.org/10.1107/S1600536810050452
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author Sun, Dajun
Han, Liying
Zang, Hu
author_facet Sun, Dajun
Han, Liying
Zang, Hu
author_sort Sun, Dajun
collection PubMed
description In the title compound, {[Ag(C(6)H(4)NO(2))(C(6)H(12)N(4))(H(2)O)]·2H(2)O}(n), the Ag(I) atom shows a distorted triangular pyramidal geometry,, formed by two N atoms from two hexa­methyl­ene­tetra­amine (hmt) ligands and one N atom from a pyridine-4-carboxyl­ate (4-pdc) ligand and one water mol­ecule. The hmt ligands bridge the Ag atoms, forming a chain along [001]. The carboxyl­ate group of the 4-pdc ligand is uncoordinated. O—H⋯O hydrogen bonds between the water mol­ecules and carboxyl­ate groups stabilize the structure.
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spelling pubmed-30503712011-04-26 catena-Poly[[[aqua­(pyridine-4-carboxyl­ato-κN)silver(I)]-μ-hexa­methyl­ene­tetra­amine-κ(2) N:N′] dihydrate] Sun, Dajun Han, Liying Zang, Hu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Ag(C(6)H(4)NO(2))(C(6)H(12)N(4))(H(2)O)]·2H(2)O}(n), the Ag(I) atom shows a distorted triangular pyramidal geometry,, formed by two N atoms from two hexa­methyl­ene­tetra­amine (hmt) ligands and one N atom from a pyridine-4-carboxyl­ate (4-pdc) ligand and one water mol­ecule. The hmt ligands bridge the Ag atoms, forming a chain along [001]. The carboxyl­ate group of the 4-pdc ligand is uncoordinated. O—H⋯O hydrogen bonds between the water mol­ecules and carboxyl­ate groups stabilize the structure. International Union of Crystallography 2010-12-08 /pmc/articles/PMC3050371/ /pubmed/21522567 http://dx.doi.org/10.1107/S1600536810050452 Text en © Sun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Dajun
Han, Liying
Zang, Hu
catena-Poly[[[aqua­(pyridine-4-carboxyl­ato-κN)silver(I)]-μ-hexa­methyl­ene­tetra­amine-κ(2) N:N′] dihydrate]
title catena-Poly[[[aqua­(pyridine-4-carboxyl­ato-κN)silver(I)]-μ-hexa­methyl­ene­tetra­amine-κ(2) N:N′] dihydrate]
title_full catena-Poly[[[aqua­(pyridine-4-carboxyl­ato-κN)silver(I)]-μ-hexa­methyl­ene­tetra­amine-κ(2) N:N′] dihydrate]
title_fullStr catena-Poly[[[aqua­(pyridine-4-carboxyl­ato-κN)silver(I)]-μ-hexa­methyl­ene­tetra­amine-κ(2) N:N′] dihydrate]
title_full_unstemmed catena-Poly[[[aqua­(pyridine-4-carboxyl­ato-κN)silver(I)]-μ-hexa­methyl­ene­tetra­amine-κ(2) N:N′] dihydrate]
title_short catena-Poly[[[aqua­(pyridine-4-carboxyl­ato-κN)silver(I)]-μ-hexa­methyl­ene­tetra­amine-κ(2) N:N′] dihydrate]
title_sort catena-poly[[[aqua­(pyridine-4-carboxyl­ato-κn)silver(i)]-μ-hexa­methyl­ene­tetra­amine-κ(2) n:n′] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050371/
https://www.ncbi.nlm.nih.gov/pubmed/21522567
http://dx.doi.org/10.1107/S1600536810050452
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AT hanliying catenapolyaquapyridine4carboxylatoknsilverimhexamethylenetetraaminek2nndihydrate
AT zanghu catenapolyaquapyridine4carboxylatoknsilverimhexamethylenetetraaminek2nndihydrate

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