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Methyl (2Z)-3-[(4-nitrophenyl)carbamoyl]prop-2-enoate
In the title compound, C(11)H(10)N(2)O(5), the amide group is nearly coplanar and the ester group approximately perpendicular to the vinyl C—HC=CH—C group [dihedral angles of 5.0 (2) and 88.89 (5)°, respectively]. This results in a short intramolecular O =C⋯O=C contact of 2.7201 (17) Å between the...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050372/ https://www.ncbi.nlm.nih.gov/pubmed/21522788 http://dx.doi.org/10.1107/S1600536810050956 |
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author | Munawar, Khurram Shahzad Ali, Saqib Tahir, M. Nawaz |
author_facet | Munawar, Khurram Shahzad Ali, Saqib Tahir, M. Nawaz |
author_sort | Munawar, Khurram Shahzad |
collection | PubMed |
description | In the title compound, C(11)H(10)N(2)O(5), the amide group is nearly coplanar and the ester group approximately perpendicular to the vinyl C—HC=CH—C group [dihedral angles of 5.0 (2) and 88.89 (5)°, respectively]. This results in a short intramolecular O =C⋯O=C contact of 2.7201 (17) Å between the amide O atom and the ester carbonyl C atom. The prop-2-enamide fragment and the nitro group make dihedral angles of 20.42 (6) and 13.54 (17)°, respectively, with the benzene ring. An intramolecular C—H⋯O interaction between the benzene ring and the amide group generates an S(6) ring motif. Intermolecular C—H⋯O and N—H⋯O hydrogen bonds complete R (2) (2)(11) ring motifs and join molecules into [100] chains. |
format | Text |
id | pubmed-3050372 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30503722011-04-26 Methyl (2Z)-3-[(4-nitrophenyl)carbamoyl]prop-2-enoate Munawar, Khurram Shahzad Ali, Saqib Tahir, M. Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(10)N(2)O(5), the amide group is nearly coplanar and the ester group approximately perpendicular to the vinyl C—HC=CH—C group [dihedral angles of 5.0 (2) and 88.89 (5)°, respectively]. This results in a short intramolecular O =C⋯O=C contact of 2.7201 (17) Å between the amide O atom and the ester carbonyl C atom. The prop-2-enamide fragment and the nitro group make dihedral angles of 20.42 (6) and 13.54 (17)°, respectively, with the benzene ring. An intramolecular C—H⋯O interaction between the benzene ring and the amide group generates an S(6) ring motif. Intermolecular C—H⋯O and N—H⋯O hydrogen bonds complete R (2) (2)(11) ring motifs and join molecules into [100] chains. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050372/ /pubmed/21522788 http://dx.doi.org/10.1107/S1600536810050956 Text en © Munawar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Munawar, Khurram Shahzad Ali, Saqib Tahir, M. Nawaz Methyl (2Z)-3-[(4-nitrophenyl)carbamoyl]prop-2-enoate |
title | Methyl (2Z)-3-[(4-nitrophenyl)carbamoyl]prop-2-enoate |
title_full | Methyl (2Z)-3-[(4-nitrophenyl)carbamoyl]prop-2-enoate |
title_fullStr | Methyl (2Z)-3-[(4-nitrophenyl)carbamoyl]prop-2-enoate |
title_full_unstemmed | Methyl (2Z)-3-[(4-nitrophenyl)carbamoyl]prop-2-enoate |
title_short | Methyl (2Z)-3-[(4-nitrophenyl)carbamoyl]prop-2-enoate |
title_sort | methyl (2z)-3-[(4-nitrophenyl)carbamoyl]prop-2-enoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050372/ https://www.ncbi.nlm.nih.gov/pubmed/21522788 http://dx.doi.org/10.1107/S1600536810050956 |
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