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Methyl (2Z)-3-[(4-nitro­phen­yl)carbamo­yl]prop-2-enoate

In the title compound, C(11)H(10)N(2)O(5), the amide group is nearly coplanar and the ester group approximately perpendicular to the vinyl C—HC=CH—C group [dihedral angles of 5.0 (2) and 88.89 (5)°, respectively]. This results in a short intra­molecular O =C⋯O=C contact of 2.7201 (17) Å between the...

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Detalles Bibliográficos
Autores principales: Munawar, Khurram Shahzad, Ali, Saqib, Tahir, M. Nawaz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050372/
https://www.ncbi.nlm.nih.gov/pubmed/21522788
http://dx.doi.org/10.1107/S1600536810050956
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author Munawar, Khurram Shahzad
Ali, Saqib
Tahir, M. Nawaz
author_facet Munawar, Khurram Shahzad
Ali, Saqib
Tahir, M. Nawaz
author_sort Munawar, Khurram Shahzad
collection PubMed
description In the title compound, C(11)H(10)N(2)O(5), the amide group is nearly coplanar and the ester group approximately perpendicular to the vinyl C—HC=CH—C group [dihedral angles of 5.0 (2) and 88.89 (5)°, respectively]. This results in a short intra­molecular O =C⋯O=C contact of 2.7201 (17) Å between the amide O atom and the ester carbonyl C atom. The prop-2-enamide fragment and the nitro group make dihedral angles of 20.42 (6) and 13.54 (17)°, respectively, with the benzene ring. An intra­molecular C—H⋯O inter­action between the benzene ring and the amide group generates an S(6) ring motif. Inter­molecular C—H⋯O and N—H⋯O hydrogen bonds complete R (2) (2)(11) ring motifs and join mol­ecules into [100] chains.
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spelling pubmed-30503722011-04-26 Methyl (2Z)-3-[(4-nitro­phen­yl)carbamo­yl]prop-2-enoate Munawar, Khurram Shahzad Ali, Saqib Tahir, M. Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(10)N(2)O(5), the amide group is nearly coplanar and the ester group approximately perpendicular to the vinyl C—HC=CH—C group [dihedral angles of 5.0 (2) and 88.89 (5)°, respectively]. This results in a short intra­molecular O =C⋯O=C contact of 2.7201 (17) Å between the amide O atom and the ester carbonyl C atom. The prop-2-enamide fragment and the nitro group make dihedral angles of 20.42 (6) and 13.54 (17)°, respectively, with the benzene ring. An intra­molecular C—H⋯O inter­action between the benzene ring and the amide group generates an S(6) ring motif. Inter­molecular C—H⋯O and N—H⋯O hydrogen bonds complete R (2) (2)(11) ring motifs and join mol­ecules into [100] chains. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050372/ /pubmed/21522788 http://dx.doi.org/10.1107/S1600536810050956 Text en © Munawar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Munawar, Khurram Shahzad
Ali, Saqib
Tahir, M. Nawaz
Methyl (2Z)-3-[(4-nitro­phen­yl)carbamo­yl]prop-2-enoate
title Methyl (2Z)-3-[(4-nitro­phen­yl)carbamo­yl]prop-2-enoate
title_full Methyl (2Z)-3-[(4-nitro­phen­yl)carbamo­yl]prop-2-enoate
title_fullStr Methyl (2Z)-3-[(4-nitro­phen­yl)carbamo­yl]prop-2-enoate
title_full_unstemmed Methyl (2Z)-3-[(4-nitro­phen­yl)carbamo­yl]prop-2-enoate
title_short Methyl (2Z)-3-[(4-nitro­phen­yl)carbamo­yl]prop-2-enoate
title_sort methyl (2z)-3-[(4-nitro­phen­yl)carbamo­yl]prop-2-enoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050372/
https://www.ncbi.nlm.nih.gov/pubmed/21522788
http://dx.doi.org/10.1107/S1600536810050956
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