rac-Ammonium cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate

In the structure of the title compound, NH(4) (+)·C(8)H(11)O(4) (−), the carboxyl and carboxyl­ate groups of the cation adopt C—C—C—O torsion angles of 174.9 (2) and −145.4 (2)°, respectively, with the alicyclic ring. The ammonium H atoms of the cations give a total of five hydrogen-bonding associat...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050381/
https://www.ncbi.nlm.nih.gov/pubmed/21522680
http://dx.doi.org/10.1107/S1600536810051883
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author Smith, Graham
Wermuth, Urs D.
author_facet Smith, Graham
Wermuth, Urs D.
author_sort Smith, Graham
collection PubMed
description In the structure of the title compound, NH(4) (+)·C(8)H(11)O(4) (−), the carboxyl and carboxyl­ate groups of the cation adopt C—C—C—O torsion angles of 174.9 (2) and −145.4 (2)°, respectively, with the alicyclic ring. The ammonium H atoms of the cations give a total of five hydrogen-bonding associations with carboxyl­ate O-atom acceptors of the anion which, together with a carboxyl O—H⋯O(carboxyl­ate) inter­action give sheet structures which lie in the (101) planes.
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spelling pubmed-30503812011-04-26 rac-Ammonium cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate Smith, Graham Wermuth, Urs D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structure of the title compound, NH(4) (+)·C(8)H(11)O(4) (−), the carboxyl and carboxyl­ate groups of the cation adopt C—C—C—O torsion angles of 174.9 (2) and −145.4 (2)°, respectively, with the alicyclic ring. The ammonium H atoms of the cations give a total of five hydrogen-bonding associations with carboxyl­ate O-atom acceptors of the anion which, together with a carboxyl O—H⋯O(carboxyl­ate) inter­action give sheet structures which lie in the (101) planes. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050381/ /pubmed/21522680 http://dx.doi.org/10.1107/S1600536810051883 Text en © Smith and Wermuth 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Smith, Graham
Wermuth, Urs D.
rac-Ammonium cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate
title rac-Ammonium cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate
title_full rac-Ammonium cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate
title_fullStr rac-Ammonium cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate
title_full_unstemmed rac-Ammonium cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate
title_short rac-Ammonium cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate
title_sort rac-ammonium cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050381/
https://www.ncbi.nlm.nih.gov/pubmed/21522680
http://dx.doi.org/10.1107/S1600536810051883
work_keys_str_mv AT smithgraham racammoniumcis2carboxycyclohexane1carboxylate
AT wermuthursd racammoniumcis2carboxycyclohexane1carboxylate

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