(η(6)-Benzene){2-[2-(tert-butyl­sulfan­yl)phenyl]pyridine-κ(2) N,S}chlorido­ruthenium(II) hexa­fluorido­phosphate

In the title compound, [RuCl(C(6)H(6))(C(15)H(17)NS)]PF(6), the cation adopts a three-legged piano-stool structure around the Ru(II) atom with an η(6)-benzene ligand, a chloride ligand and a 2-[2-(tert-butyl­sulfan­yl)phen­yl]pyridine (btppy) ligand. The btppy ligand acts as a N,S-bidentate ligand,...

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Detalles Bibliográficos
Autores principales: Hirotsu, Masakazu, Yogi, Akira, Kinoshita, Isamu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050383/
https://www.ncbi.nlm.nih.gov/pubmed/21522582
http://dx.doi.org/10.1107/S1600536810049810
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author Hirotsu, Masakazu
Yogi, Akira
Kinoshita, Isamu
author_facet Hirotsu, Masakazu
Yogi, Akira
Kinoshita, Isamu
author_sort Hirotsu, Masakazu
collection PubMed
description In the title compound, [RuCl(C(6)H(6))(C(15)H(17)NS)]PF(6), the cation adopts a three-legged piano-stool structure around the Ru(II) atom with an η(6)-benzene ligand, a chloride ligand and a 2-[2-(tert-butyl­sulfan­yl)phen­yl]pyridine (btppy) ligand. The btppy ligand acts as a N,S-bidentate ligand, forming a six-membered ring, which has an envelope conformation. The S—Ru—N bite angle is 86.76 (9)°, and the dihedral angle between the pyridine and benzene rings in btppy is 39.8 (2)°. The unit cell contains two pairs of racemic diastereomers with (S (Ru),S (S)) and (R (Ru),R (S)) configurations, in which the tert-butyl group on the coordin­ated S atom is distant from the η(6)-benzene ligand.
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spelling pubmed-30503832011-04-26 (η(6)-Benzene){2-[2-(tert-butyl­sulfan­yl)phenyl]pyridine-κ(2) N,S}chlorido­ruthenium(II) hexa­fluorido­phosphate Hirotsu, Masakazu Yogi, Akira Kinoshita, Isamu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RuCl(C(6)H(6))(C(15)H(17)NS)]PF(6), the cation adopts a three-legged piano-stool structure around the Ru(II) atom with an η(6)-benzene ligand, a chloride ligand and a 2-[2-(tert-butyl­sulfan­yl)phen­yl]pyridine (btppy) ligand. The btppy ligand acts as a N,S-bidentate ligand, forming a six-membered ring, which has an envelope conformation. The S—Ru—N bite angle is 86.76 (9)°, and the dihedral angle between the pyridine and benzene rings in btppy is 39.8 (2)°. The unit cell contains two pairs of racemic diastereomers with (S (Ru),S (S)) and (R (Ru),R (S)) configurations, in which the tert-butyl group on the coordin­ated S atom is distant from the η(6)-benzene ligand. International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050383/ /pubmed/21522582 http://dx.doi.org/10.1107/S1600536810049810 Text en © Hirotsu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hirotsu, Masakazu
Yogi, Akira
Kinoshita, Isamu
(η(6)-Benzene){2-[2-(tert-butyl­sulfan­yl)phenyl]pyridine-κ(2) N,S}chlorido­ruthenium(II) hexa­fluorido­phosphate
title (η(6)-Benzene){2-[2-(tert-butyl­sulfan­yl)phenyl]pyridine-κ(2) N,S}chlorido­ruthenium(II) hexa­fluorido­phosphate
title_full (η(6)-Benzene){2-[2-(tert-butyl­sulfan­yl)phenyl]pyridine-κ(2) N,S}chlorido­ruthenium(II) hexa­fluorido­phosphate
title_fullStr (η(6)-Benzene){2-[2-(tert-butyl­sulfan­yl)phenyl]pyridine-κ(2) N,S}chlorido­ruthenium(II) hexa­fluorido­phosphate
title_full_unstemmed (η(6)-Benzene){2-[2-(tert-butyl­sulfan­yl)phenyl]pyridine-κ(2) N,S}chlorido­ruthenium(II) hexa­fluorido­phosphate
title_short (η(6)-Benzene){2-[2-(tert-butyl­sulfan­yl)phenyl]pyridine-κ(2) N,S}chlorido­ruthenium(II) hexa­fluorido­phosphate
title_sort (η(6)-benzene){2-[2-(tert-butyl­sulfan­yl)phenyl]pyridine-κ(2) n,s}chlorido­ruthenium(ii) hexa­fluorido­phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050383/
https://www.ncbi.nlm.nih.gov/pubmed/21522582
http://dx.doi.org/10.1107/S1600536810049810
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AT kinoshitaisamu ē6benzene22tertbutylsulfanylphenylpyridinek2nschloridorutheniumiihexafluoridophosphate

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