fac-{2-[Bis(2-amino­eth­yl)amino]­ethanaminium}trichloridorhodium(III) chloride hemihydrate

The crystal structure of the title compound, [Rh(C(6)H(19)N(4))Cl(3)]Cl·0.5H(2)O, is isotypic with the previously reported Ru analogue. The structure contains two crystallographically independent [Rh(Htren)Cl(3)](+) cations with a facial tridentate coordination of the monoprotonated tren ligand [tre...

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Detalles Bibliográficos
Autores principales: Kutzky, Barbara, Neis, Christian, Hegetschweiler, Kaspar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050386/
https://www.ncbi.nlm.nih.gov/pubmed/21522607
http://dx.doi.org/10.1107/S1600536810051846
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author Kutzky, Barbara
Neis, Christian
Hegetschweiler, Kaspar
author_facet Kutzky, Barbara
Neis, Christian
Hegetschweiler, Kaspar
author_sort Kutzky, Barbara
collection PubMed
description The crystal structure of the title compound, [Rh(C(6)H(19)N(4))Cl(3)]Cl·0.5H(2)O, is isotypic with the previously reported Ru analogue. The structure contains two crystallographically independent [Rh(Htren)Cl(3)](+) cations with a facial tridentate coordination of the monoprotonated tren ligand [tren = tris­(2-amino­eth­yl)amine], leading to an overall distorted octahedral coordination environment around the Rh(III) atom. In one of the two cations, the ethyl­ene groups of the two chelate rings as well as the non-coordinating ethyl­ammonium group are disordered over two sets of sites [0.579 (3):0.421 (3) occupancy ratio]. A series of N—H⋯Cl and O—H⋯Cl hydrogen bonds stabilizes the structure.
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spelling pubmed-30503862011-04-26 fac-{2-[Bis(2-amino­eth­yl)amino]­ethanaminium}trichloridorhodium(III) chloride hemihydrate Kutzky, Barbara Neis, Christian Hegetschweiler, Kaspar Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Rh(C(6)H(19)N(4))Cl(3)]Cl·0.5H(2)O, is isotypic with the previously reported Ru analogue. The structure contains two crystallographically independent [Rh(Htren)Cl(3)](+) cations with a facial tridentate coordination of the monoprotonated tren ligand [tren = tris­(2-amino­eth­yl)amine], leading to an overall distorted octahedral coordination environment around the Rh(III) atom. In one of the two cations, the ethyl­ene groups of the two chelate rings as well as the non-coordinating ethyl­ammonium group are disordered over two sets of sites [0.579 (3):0.421 (3) occupancy ratio]. A series of N—H⋯Cl and O—H⋯Cl hydrogen bonds stabilizes the structure. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050386/ /pubmed/21522607 http://dx.doi.org/10.1107/S1600536810051846 Text en © Kutzky et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kutzky, Barbara
Neis, Christian
Hegetschweiler, Kaspar
fac-{2-[Bis(2-amino­eth­yl)amino]­ethanaminium}trichloridorhodium(III) chloride hemihydrate
title fac-{2-[Bis(2-amino­eth­yl)amino]­ethanaminium}trichloridorhodium(III) chloride hemihydrate
title_full fac-{2-[Bis(2-amino­eth­yl)amino]­ethanaminium}trichloridorhodium(III) chloride hemihydrate
title_fullStr fac-{2-[Bis(2-amino­eth­yl)amino]­ethanaminium}trichloridorhodium(III) chloride hemihydrate
title_full_unstemmed fac-{2-[Bis(2-amino­eth­yl)amino]­ethanaminium}trichloridorhodium(III) chloride hemihydrate
title_short fac-{2-[Bis(2-amino­eth­yl)amino]­ethanaminium}trichloridorhodium(III) chloride hemihydrate
title_sort fac-{2-[bis(2-amino­eth­yl)amino]­ethanaminium}trichloridorhodium(iii) chloride hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050386/
https://www.ncbi.nlm.nih.gov/pubmed/21522607
http://dx.doi.org/10.1107/S1600536810051846
work_keys_str_mv AT kutzkybarbara fac2bis2aminoethylaminoethanaminiumtrichloridorhodiumiiichloridehemihydrate
AT neischristian fac2bis2aminoethylaminoethanaminiumtrichloridorhodiumiiichloridehemihydrate
AT hegetschweilerkaspar fac2bis2aminoethylaminoethanaminiumtrichloridorhodiumiiichloridehemihydrate

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