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Bis(μ-3,5-dinitrobenzoato-κ(2) O (1):O (1′))bis(μ-3,5-dinitrobenzoato)-κ(3) O (1),O (1′):O (1);κ(3) O (1):O (1),O (1′)-bis[(3,5-dinitrobenzoato-κ(2) O (1),O (1′))(1,10-phenanthroline-κ(2) N,N)dysprosium(III)]
In the binuclear title complex, [Dy(2)(C(7)H(3)N(2)O(6))(6)(C(12)H(8)N(2))(2)], the Dy(III) ions exhibit a distorted monocapped square-antiprismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand. The carboxylate gr...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050390/ https://www.ncbi.nlm.nih.gov/pubmed/21522517 http://dx.doi.org/10.1107/S1600536810052001 |
| _version_ | 1782199352993775616 |
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| author | Dong, Chun-Hua Zhang, Da-Hai Ren, Ning Xi, Gai-Qing Hao, Juan-Juan |
| author_facet | Dong, Chun-Hua Zhang, Da-Hai Ren, Ning Xi, Gai-Qing Hao, Juan-Juan |
| author_sort | Dong, Chun-Hua |
| collection | PubMed |
| description | In the binuclear title complex, [Dy(2)(C(7)H(3)N(2)O(6))(6)(C(12)H(8)N(2))(2)], the Dy(III) ions exhibit a distorted monocapped square-antiprismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand. The carboxylate groups of the DNBA anions exhibit three coordination modes: bidentate chelating, bidentate chelating–bridging and tridentate chelating–bridging. The center of the molecule is located on a crystallographic center of inversion. |
| format | Text |
| id | pubmed-3050390 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30503902011-04-26 Bis(μ-3,5-dinitrobenzoato-κ(2) O (1):O (1′))bis(μ-3,5-dinitrobenzoato)-κ(3) O (1),O (1′):O (1);κ(3) O (1):O (1),O (1′)-bis[(3,5-dinitrobenzoato-κ(2) O (1),O (1′))(1,10-phenanthroline-κ(2) N,N)dysprosium(III)] Dong, Chun-Hua Zhang, Da-Hai Ren, Ning Xi, Gai-Qing Hao, Juan-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear title complex, [Dy(2)(C(7)H(3)N(2)O(6))(6)(C(12)H(8)N(2))(2)], the Dy(III) ions exhibit a distorted monocapped square-antiprismatic geometry and are coordinated by seven O atoms of four 3,5-dinitrobenzoate (DNBA) anions and two N atoms of a phenanthroline ligand. The carboxylate groups of the DNBA anions exhibit three coordination modes: bidentate chelating, bidentate chelating–bridging and tridentate chelating–bridging. The center of the molecule is located on a crystallographic center of inversion. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050390/ /pubmed/21522517 http://dx.doi.org/10.1107/S1600536810052001 Text en © Dong et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Dong, Chun-Hua Zhang, Da-Hai Ren, Ning Xi, Gai-Qing Hao, Juan-Juan Bis(μ-3,5-dinitrobenzoato-κ(2) O (1):O (1′))bis(μ-3,5-dinitrobenzoato)-κ(3) O (1),O (1′):O (1);κ(3) O (1):O (1),O (1′)-bis[(3,5-dinitrobenzoato-κ(2) O (1),O (1′))(1,10-phenanthroline-κ(2) N,N)dysprosium(III)] |
| title | Bis(μ-3,5-dinitrobenzoato-κ(2)
O
(1):O
(1′))bis(μ-3,5-dinitrobenzoato)-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[(3,5-dinitrobenzoato-κ(2)
O
(1),O
(1′))(1,10-phenanthroline-κ(2)
N,N)dysprosium(III)] |
| title_full | Bis(μ-3,5-dinitrobenzoato-κ(2)
O
(1):O
(1′))bis(μ-3,5-dinitrobenzoato)-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[(3,5-dinitrobenzoato-κ(2)
O
(1),O
(1′))(1,10-phenanthroline-κ(2)
N,N)dysprosium(III)] |
| title_fullStr | Bis(μ-3,5-dinitrobenzoato-κ(2)
O
(1):O
(1′))bis(μ-3,5-dinitrobenzoato)-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[(3,5-dinitrobenzoato-κ(2)
O
(1),O
(1′))(1,10-phenanthroline-κ(2)
N,N)dysprosium(III)] |
| title_full_unstemmed | Bis(μ-3,5-dinitrobenzoato-κ(2)
O
(1):O
(1′))bis(μ-3,5-dinitrobenzoato)-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[(3,5-dinitrobenzoato-κ(2)
O
(1),O
(1′))(1,10-phenanthroline-κ(2)
N,N)dysprosium(III)] |
| title_short | Bis(μ-3,5-dinitrobenzoato-κ(2)
O
(1):O
(1′))bis(μ-3,5-dinitrobenzoato)-κ(3)
O
(1),O
(1′):O
(1);κ(3)
O
(1):O
(1),O
(1′)-bis[(3,5-dinitrobenzoato-κ(2)
O
(1),O
(1′))(1,10-phenanthroline-κ(2)
N,N)dysprosium(III)] |
| title_sort | bis(μ-3,5-dinitrobenzoato-κ(2)
o
(1):o
(1′))bis(μ-3,5-dinitrobenzoato)-κ(3)
o
(1),o
(1′):o
(1);κ(3)
o
(1):o
(1),o
(1′)-bis[(3,5-dinitrobenzoato-κ(2)
o
(1),o
(1′))(1,10-phenanthroline-κ(2)
n,n)dysprosium(iii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050390/ https://www.ncbi.nlm.nih.gov/pubmed/21522517 http://dx.doi.org/10.1107/S1600536810052001 |
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