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Aqua­(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(formato-κ(2) O,O′)(formato-κO)cobalt(II) monohydrate

The asymmetric unit of the title compound, [Co(HCO(2))(2)(C(14)H(12)N(2))(H(2)O)]·H(2)O, contains a mononuclear complex mol­ecule hydrogen bonded to a lattice water mol­ecule. The Co(II) cation is in a distorted octa­hedral coordination environment defined by the two N atoms of the 2,9-dimethyl-1,10...

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Detalles Bibliográficos
Autores principales: Ni, Sheng-Liang, Xia, Ping, Cao, Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050392/
https://www.ncbi.nlm.nih.gov/pubmed/21522561
http://dx.doi.org/10.1107/S1600536810050051
Descripción
Sumario:The asymmetric unit of the title compound, [Co(HCO(2))(2)(C(14)H(12)N(2))(H(2)O)]·H(2)O, contains a mononuclear complex mol­ecule hydrogen bonded to a lattice water mol­ecule. The Co(II) cation is in a distorted octa­hedral coordination environment defined by the two N atoms of the 2,9-dimethyl-1,10-phenanthroline ligand and four O atoms. Two of these are from a chelating formate anion, one from a monodentate formate and the last from an aqua ligand. In the crystal, mol­ecules are connected by O—H⋯O hydrogen bonds, forming double chains along [100] with the 2,9-dimethyl-1,10-phenanthroline ligands pointing outwards from each chain. These chains are further linked into layers parallel to (011) by inter-chain π–π stacking inter­actions with centroid–centroid distances of 3.61 (1) Å.