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Aqua(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(formato-κ(2) O,O′)(formato-κO)cobalt(II) monohydrate
The asymmetric unit of the title compound, [Co(HCO(2))(2)(C(14)H(12)N(2))(H(2)O)]·H(2)O, contains a mononuclear complex molecule hydrogen bonded to a lattice water molecule. The Co(II) cation is in a distorted octahedral coordination environment defined by the two N atoms of the 2,9-dimethyl-1,10...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050392/ https://www.ncbi.nlm.nih.gov/pubmed/21522561 http://dx.doi.org/10.1107/S1600536810050051 |
Sumario: | The asymmetric unit of the title compound, [Co(HCO(2))(2)(C(14)H(12)N(2))(H(2)O)]·H(2)O, contains a mononuclear complex molecule hydrogen bonded to a lattice water molecule. The Co(II) cation is in a distorted octahedral coordination environment defined by the two N atoms of the 2,9-dimethyl-1,10-phenanthroline ligand and four O atoms. Two of these are from a chelating formate anion, one from a monodentate formate and the last from an aqua ligand. In the crystal, molecules are connected by O—H⋯O hydrogen bonds, forming double chains along [100] with the 2,9-dimethyl-1,10-phenanthroline ligands pointing outwards from each chain. These chains are further linked into layers parallel to (011) by inter-chain π–π stacking interactions with centroid–centroid distances of 3.61 (1) Å. |
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