[μ-1,2-Bis(diphenyl­phosphan­yl)benzene-κ(2) P:P′]bis­[chloridogold(I)]

In the crystal structure of the non-solvate form of the title compound, [Au(2)Cl(2)(C(30)H(24)P(2))], two almost linear P—Au(I)—Cl units [175.87 (3) and 171.48 (3)°] are in a skewed arrangement with a Cl—Au⋯Au—Cl torsion angle of −65.29 (3)° so as to form an intra­molecular Au⋯Au inter­action [3.056...

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Detalles Bibliográficos
Autores principales: Yoshinari, Nobuto, Kitani, Naoki, Tsukuda, Toshiaki, Konno, Takumi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050393/
https://www.ncbi.nlm.nih.gov/pubmed/21522532
http://dx.doi.org/10.1107/S1600536810052803
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author Yoshinari, Nobuto
Kitani, Naoki
Tsukuda, Toshiaki
Konno, Takumi
author_facet Yoshinari, Nobuto
Kitani, Naoki
Tsukuda, Toshiaki
Konno, Takumi
author_sort Yoshinari, Nobuto
collection PubMed
description In the crystal structure of the non-solvate form of the title compound, [Au(2)Cl(2)(C(30)H(24)P(2))], two almost linear P—Au(I)—Cl units [175.87 (3) and 171.48 (3)°] are in a skewed arrangement with a Cl—Au⋯Au—Cl torsion angle of −65.29 (3)° so as to form an intra­molecular Au⋯Au inter­action [3.0563 (2) Å]. The complex mol­ecules are connected each other through inter­molecular C—H⋯π inter­actions, giving a sheet structure parallel to the bc plane.
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spelling pubmed-30503932011-04-26 [μ-1,2-Bis(diphenyl­phosphan­yl)benzene-κ(2) P:P′]bis­[chloridogold(I)] Yoshinari, Nobuto Kitani, Naoki Tsukuda, Toshiaki Konno, Takumi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the non-solvate form of the title compound, [Au(2)Cl(2)(C(30)H(24)P(2))], two almost linear P—Au(I)—Cl units [175.87 (3) and 171.48 (3)°] are in a skewed arrangement with a Cl—Au⋯Au—Cl torsion angle of −65.29 (3)° so as to form an intra­molecular Au⋯Au inter­action [3.0563 (2) Å]. The complex mol­ecules are connected each other through inter­molecular C—H⋯π inter­actions, giving a sheet structure parallel to the bc plane. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050393/ /pubmed/21522532 http://dx.doi.org/10.1107/S1600536810052803 Text en © Yoshinari et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yoshinari, Nobuto
Kitani, Naoki
Tsukuda, Toshiaki
Konno, Takumi
[μ-1,2-Bis(diphenyl­phosphan­yl)benzene-κ(2) P:P′]bis­[chloridogold(I)]
title [μ-1,2-Bis(diphenyl­phosphan­yl)benzene-κ(2) P:P′]bis­[chloridogold(I)]
title_full [μ-1,2-Bis(diphenyl­phosphan­yl)benzene-κ(2) P:P′]bis­[chloridogold(I)]
title_fullStr [μ-1,2-Bis(diphenyl­phosphan­yl)benzene-κ(2) P:P′]bis­[chloridogold(I)]
title_full_unstemmed [μ-1,2-Bis(diphenyl­phosphan­yl)benzene-κ(2) P:P′]bis­[chloridogold(I)]
title_short [μ-1,2-Bis(diphenyl­phosphan­yl)benzene-κ(2) P:P′]bis­[chloridogold(I)]
title_sort [μ-1,2-bis(diphenyl­phosphan­yl)benzene-κ(2) p:p′]bis­[chloridogold(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050393/
https://www.ncbi.nlm.nih.gov/pubmed/21522532
http://dx.doi.org/10.1107/S1600536810052803
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AT tsukudatoshiaki m12bisdiphenylphosphanylbenzenek2ppbischloridogoldi
AT konnotakumi m12bisdiphenylphosphanylbenzenek2ppbischloridogoldi

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