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3-(2,4-Dichlorophenoxy)-1-(4-methoxyphenyl)-4-(3-nitrophenyl)azetidin-2-one
In the title compound, C(22)H(16)Cl(2)N(2)O(5), the nearly planar four-membered β-lactam ring [maximum deviations of 0.011 (2) for the N atom] makes dihedral angles of 68.34 (13), 83.04 (13) and 3.37 (13)° with the dichloro-, nitro- and methoxyphenyl rings, respectively. The crystal structure is s...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050394/ https://www.ncbi.nlm.nih.gov/pubmed/21522688 http://dx.doi.org/10.1107/S1600536810052645 |
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author | Akkurt, Mehmet Türktekin, Sevim Jarrahpour, Aliasghar Badrabady, Seid Ali Torabi Büyükgüngör, Orhan |
author_facet | Akkurt, Mehmet Türktekin, Sevim Jarrahpour, Aliasghar Badrabady, Seid Ali Torabi Büyükgüngör, Orhan |
author_sort | Akkurt, Mehmet |
collection | PubMed |
description | In the title compound, C(22)H(16)Cl(2)N(2)O(5), the nearly planar four-membered β-lactam ring [maximum deviations of 0.011 (2) for the N atom] makes dihedral angles of 68.34 (13), 83.04 (13) and 3.37 (13)° with the dichloro-, nitro- and methoxyphenyl rings, respectively. The crystal structure is stabilized by C—H⋯O hydrogen-bond interactions. In addition, a π–π stacking interaction [centroid–centroid distance = 3.6622 (12) Å] is observed between the β-lactam and nitrophenyl rings. |
format | Text |
id | pubmed-3050394 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30503942011-04-26 3-(2,4-Dichlorophenoxy)-1-(4-methoxyphenyl)-4-(3-nitrophenyl)azetidin-2-one Akkurt, Mehmet Türktekin, Sevim Jarrahpour, Aliasghar Badrabady, Seid Ali Torabi Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(16)Cl(2)N(2)O(5), the nearly planar four-membered β-lactam ring [maximum deviations of 0.011 (2) for the N atom] makes dihedral angles of 68.34 (13), 83.04 (13) and 3.37 (13)° with the dichloro-, nitro- and methoxyphenyl rings, respectively. The crystal structure is stabilized by C—H⋯O hydrogen-bond interactions. In addition, a π–π stacking interaction [centroid–centroid distance = 3.6622 (12) Å] is observed between the β-lactam and nitrophenyl rings. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050394/ /pubmed/21522688 http://dx.doi.org/10.1107/S1600536810052645 Text en © Akkurt et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Akkurt, Mehmet Türktekin, Sevim Jarrahpour, Aliasghar Badrabady, Seid Ali Torabi Büyükgüngör, Orhan 3-(2,4-Dichlorophenoxy)-1-(4-methoxyphenyl)-4-(3-nitrophenyl)azetidin-2-one |
title | 3-(2,4-Dichlorophenoxy)-1-(4-methoxyphenyl)-4-(3-nitrophenyl)azetidin-2-one |
title_full | 3-(2,4-Dichlorophenoxy)-1-(4-methoxyphenyl)-4-(3-nitrophenyl)azetidin-2-one |
title_fullStr | 3-(2,4-Dichlorophenoxy)-1-(4-methoxyphenyl)-4-(3-nitrophenyl)azetidin-2-one |
title_full_unstemmed | 3-(2,4-Dichlorophenoxy)-1-(4-methoxyphenyl)-4-(3-nitrophenyl)azetidin-2-one |
title_short | 3-(2,4-Dichlorophenoxy)-1-(4-methoxyphenyl)-4-(3-nitrophenyl)azetidin-2-one |
title_sort | 3-(2,4-dichlorophenoxy)-1-(4-methoxyphenyl)-4-(3-nitrophenyl)azetidin-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050394/ https://www.ncbi.nlm.nih.gov/pubmed/21522688 http://dx.doi.org/10.1107/S1600536810052645 |
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