4-Carbamoylpiperidinium 5-nitro­salicylate

In the crystal structure of the title compound, C(6)H(13)N(2)O(+)·C(7)H(4)NO(5) (−), the isonipecotamide cations and the 5-nitro­salicylate anions form hydrogen-bonded chain substructures through head-to-tail piperidinium–carboxyl­ate N—H⋯O hydrogen bonds and through centrosymmetric cyclic head-to-h...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050397/
https://www.ncbi.nlm.nih.gov/pubmed/21522633
http://dx.doi.org/10.1107/S1600536810050129
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author Smith, Graham
Wermuth, Urs D.
author_facet Smith, Graham
Wermuth, Urs D.
author_sort Smith, Graham
collection PubMed
description In the crystal structure of the title compound, C(6)H(13)N(2)O(+)·C(7)H(4)NO(5) (−), the isonipecotamide cations and the 5-nitro­salicylate anions form hydrogen-bonded chain substructures through head-to-tail piperidinium–carboxyl­ate N—H⋯O hydrogen bonds and through centrosymmetric cyclic head-to-head amide–amide hydrogen-bonding associations [graph set R (2) (2)(8)]. These chains are cross-linked by amide–carboxyl­ate N—H⋯O and piperidinium–nitro N—H⋯O associations, giving a sheet structure.
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spelling pubmed-30503972011-04-26 4-Carbamoylpiperidinium 5-nitro­salicylate Smith, Graham Wermuth, Urs D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(6)H(13)N(2)O(+)·C(7)H(4)NO(5) (−), the isonipecotamide cations and the 5-nitro­salicylate anions form hydrogen-bonded chain substructures through head-to-tail piperidinium–carboxyl­ate N—H⋯O hydrogen bonds and through centrosymmetric cyclic head-to-head amide–amide hydrogen-bonding associations [graph set R (2) (2)(8)]. These chains are cross-linked by amide–carboxyl­ate N—H⋯O and piperidinium–nitro N—H⋯O associations, giving a sheet structure. International Union of Crystallography 2010-12-15 /pmc/articles/PMC3050397/ /pubmed/21522633 http://dx.doi.org/10.1107/S1600536810050129 Text en © Smith and Wermuth 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Smith, Graham
Wermuth, Urs D.
4-Carbamoylpiperidinium 5-nitro­salicylate
title 4-Carbamoylpiperidinium 5-nitro­salicylate
title_full 4-Carbamoylpiperidinium 5-nitro­salicylate
title_fullStr 4-Carbamoylpiperidinium 5-nitro­salicylate
title_full_unstemmed 4-Carbamoylpiperidinium 5-nitro­salicylate
title_short 4-Carbamoylpiperidinium 5-nitro­salicylate
title_sort 4-carbamoylpiperidinium 5-nitro­salicylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050397/
https://www.ncbi.nlm.nih.gov/pubmed/21522633
http://dx.doi.org/10.1107/S1600536810050129
work_keys_str_mv AT smithgraham 4carbamoylpiperidinium5nitrosalicylate
AT wermuthursd 4carbamoylpiperidinium5nitrosalicylate

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