Dichlorido(η(6)-p-cymene)(4-fluoro­aniline-κN)ruthenium(II)

The title compound, [RuCl(2)(C(10)H(14))(C(6)H(6)FN)], a pseudo-octa­hedral d (6) complex, has the expected piano-stool geometry around the Ru(II) atom. The fluoro­aniline ring forms a dihedral angle of 19.3 (2)° with the p-cymene ring. In the crystal, two mol­ecules form an inversion dimer via a pa...

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Detalles Bibliográficos
Autores principales: Sykora, Richard E., Harris, Andrew G., Clements, Jason W., Hoffman, Norris W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050405/
https://www.ncbi.nlm.nih.gov/pubmed/21522611
http://dx.doi.org/10.1107/S1600536810051962
Descripción
Sumario:The title compound, [RuCl(2)(C(10)H(14))(C(6)H(6)FN)], a pseudo-octa­hedral d (6) complex, has the expected piano-stool geometry around the Ru(II) atom. The fluoro­aniline ring forms a dihedral angle of 19.3 (2)° with the p-cymene ring. In the crystal, two mol­ecules form an inversion dimer via a pair of N—H⋯Cl hydrogen bonds. Weak inter­molecular C—H⋯Cl inter­actions involving the p-cymene ring consolidate the crystal packing.

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