Dichlorido(η(6)-p-cymene)(4-fluoro­aniline-κN)ruthenium(II)

The title compound, [RuCl(2)(C(10)H(14))(C(6)H(6)FN)], a pseudo-octa­hedral d (6) complex, has the expected piano-stool geometry around the Ru(II) atom. The fluoro­aniline ring forms a dihedral angle of 19.3 (2)° with the p-cymene ring. In the crystal, two mol­ecules form an inversion dimer via a pa...

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Detalles Bibliográficos
Autores principales: Sykora, Richard E., Harris, Andrew G., Clements, Jason W., Hoffman, Norris W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050405/
https://www.ncbi.nlm.nih.gov/pubmed/21522611
http://dx.doi.org/10.1107/S1600536810051962
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author Sykora, Richard E.
Harris, Andrew G.
Clements, Jason W.
Hoffman, Norris W.
author_facet Sykora, Richard E.
Harris, Andrew G.
Clements, Jason W.
Hoffman, Norris W.
author_sort Sykora, Richard E.
collection PubMed
description The title compound, [RuCl(2)(C(10)H(14))(C(6)H(6)FN)], a pseudo-octa­hedral d (6) complex, has the expected piano-stool geometry around the Ru(II) atom. The fluoro­aniline ring forms a dihedral angle of 19.3 (2)° with the p-cymene ring. In the crystal, two mol­ecules form an inversion dimer via a pair of N—H⋯Cl hydrogen bonds. Weak inter­molecular C—H⋯Cl inter­actions involving the p-cymene ring consolidate the crystal packing.
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spelling pubmed-30504052011-04-26 Dichlorido(η(6)-p-cymene)(4-fluoro­aniline-κN)ruthenium(II) Sykora, Richard E. Harris, Andrew G. Clements, Jason W. Hoffman, Norris W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [RuCl(2)(C(10)H(14))(C(6)H(6)FN)], a pseudo-octa­hedral d (6) complex, has the expected piano-stool geometry around the Ru(II) atom. The fluoro­aniline ring forms a dihedral angle of 19.3 (2)° with the p-cymene ring. In the crystal, two mol­ecules form an inversion dimer via a pair of N—H⋯Cl hydrogen bonds. Weak inter­molecular C—H⋯Cl inter­actions involving the p-cymene ring consolidate the crystal packing. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050405/ /pubmed/21522611 http://dx.doi.org/10.1107/S1600536810051962 Text en © Sykora et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sykora, Richard E.
Harris, Andrew G.
Clements, Jason W.
Hoffman, Norris W.
Dichlorido(η(6)-p-cymene)(4-fluoro­aniline-κN)ruthenium(II)
title Dichlorido(η(6)-p-cymene)(4-fluoro­aniline-κN)ruthenium(II)
title_full Dichlorido(η(6)-p-cymene)(4-fluoro­aniline-κN)ruthenium(II)
title_fullStr Dichlorido(η(6)-p-cymene)(4-fluoro­aniline-κN)ruthenium(II)
title_full_unstemmed Dichlorido(η(6)-p-cymene)(4-fluoro­aniline-κN)ruthenium(II)
title_short Dichlorido(η(6)-p-cymene)(4-fluoro­aniline-κN)ruthenium(II)
title_sort dichlorido(η(6)-p-cymene)(4-fluoro­aniline-κn)ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050405/
https://www.ncbi.nlm.nih.gov/pubmed/21522611
http://dx.doi.org/10.1107/S1600536810051962
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AT hoffmannorrisw dichloridoē6pcymene4fluoroanilineknrutheniumii

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