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Di-μ-thiocyanato-bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane]silver(I)}
The title compound, [Ag(2)(NCS)(2)(C(14)H(38)B(10)P(2))(2)], was synthesized by the reaction of 1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane with AgSCN. The diisopropylphosphanyl-closo-carborane ligand is coordinated in a bidentate manner to the Ag(I) atom through the two P a...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050408/ https://www.ncbi.nlm.nih.gov/pubmed/21522546 http://dx.doi.org/10.1107/S1600536810049263 |
Sumario: | The title compound, [Ag(2)(NCS)(2)(C(14)H(38)B(10)P(2))(2)], was synthesized by the reaction of 1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane with AgSCN. The diisopropylphosphanyl-closo-carborane ligand is coordinated in a bidentate manner to the Ag(I) atom through the two P atoms. The coordination of the Ag(I) atom is distorted tetrahedral, in which two vertices are formed by the P atoms of the chelating diphosphine ligand, and the other two are occupied by the S and N atoms of the two bridging thiocyanate anions, leading to a centrosymmetric binuclear complex. The distance between the two C atoms in the carborane skeleton is 1.851 (6) Å. |
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