Di-μ-thio­cyanato-bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane]silver(I)}

The title compound, [Ag(2)(NCS)(2)(C(14)H(38)B(10)P(2))(2)], was synthesized by the reaction of 1,2-bis­(diiso­propyl­phos­phan­yl)-1,2-dicarba-closo-dodeca­borane with AgSCN. The diisopropyl­phosphanyl-closo-carborane ligand is coordinated in a bidentate manner to the Ag(I) atom through the two P a...

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Detalles Bibliográficos
Autores principales: Yang, Liguo, Zhu, Chengchen, Li, Dacheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050408/
https://www.ncbi.nlm.nih.gov/pubmed/21522546
http://dx.doi.org/10.1107/S1600536810049263
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author Yang, Liguo
Zhu, Chengchen
Li, Dacheng
author_facet Yang, Liguo
Zhu, Chengchen
Li, Dacheng
author_sort Yang, Liguo
collection PubMed
description The title compound, [Ag(2)(NCS)(2)(C(14)H(38)B(10)P(2))(2)], was synthesized by the reaction of 1,2-bis­(diiso­propyl­phos­phan­yl)-1,2-dicarba-closo-dodeca­borane with AgSCN. The diisopropyl­phosphanyl-closo-carborane ligand is coordinated in a bidentate manner to the Ag(I) atom through the two P atoms. The coordination of the Ag(I) atom is distorted tetra­hedral, in which two vertices are formed by the P atoms of the chelating diphosphine ligand, and the other two are occupied by the S and N atoms of the two bridging thio­cyanate anions, leading to a centrosymmetric binuclear complex. The distance between the two C atoms in the carborane skeleton is 1.851 (6) Å.
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spelling pubmed-30504082011-04-26 Di-μ-thio­cyanato-bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane]silver(I)} Yang, Liguo Zhu, Chengchen Li, Dacheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ag(2)(NCS)(2)(C(14)H(38)B(10)P(2))(2)], was synthesized by the reaction of 1,2-bis­(diiso­propyl­phos­phan­yl)-1,2-dicarba-closo-dodeca­borane with AgSCN. The diisopropyl­phosphanyl-closo-carborane ligand is coordinated in a bidentate manner to the Ag(I) atom through the two P atoms. The coordination of the Ag(I) atom is distorted tetra­hedral, in which two vertices are formed by the P atoms of the chelating diphosphine ligand, and the other two are occupied by the S and N atoms of the two bridging thio­cyanate anions, leading to a centrosymmetric binuclear complex. The distance between the two C atoms in the carborane skeleton is 1.851 (6) Å. International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050408/ /pubmed/21522546 http://dx.doi.org/10.1107/S1600536810049263 Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Liguo
Zhu, Chengchen
Li, Dacheng
Di-μ-thio­cyanato-bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane]silver(I)}
title Di-μ-thio­cyanato-bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane]silver(I)}
title_full Di-μ-thio­cyanato-bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane]silver(I)}
title_fullStr Di-μ-thio­cyanato-bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane]silver(I)}
title_full_unstemmed Di-μ-thio­cyanato-bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane]silver(I)}
title_short Di-μ-thio­cyanato-bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane]silver(I)}
title_sort di-μ-thio­cyanato-bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane]silver(i)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050408/
https://www.ncbi.nlm.nih.gov/pubmed/21522546
http://dx.doi.org/10.1107/S1600536810049263
work_keys_str_mv AT yangliguo dimthiocyanatobis12bisdiisopropylphosphanyl12dicarbaclosododecaboranesilveri
AT zhuchengchen dimthiocyanatobis12bisdiisopropylphosphanyl12dicarbaclosododecaboranesilveri
AT lidacheng dimthiocyanatobis12bisdiisopropylphosphanyl12dicarbaclosododecaboranesilveri

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