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Di-μ-aqua-bis­{triaqua­[5-(1-oxopyridin-4-yl)tetra­zol-1-ido]sodium}

In the title compound, [Na(2)(C(6)H(4)N(5)O)(2)(H(2)O)(8)], the Na(I) atom is in a distorted octahedral environment defined by six O atoms, one from the 5-(1-oxopyridin-4-yl)tetra­zolide anion and five from water mol­ecules. Two water mol­ecules act as bridging ligands, resulting in the formation of...

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Detalles Bibliográficos
Autores principales: Dai, Jing, Chen, Xin-Yuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050412/
https://www.ncbi.nlm.nih.gov/pubmed/21522524
http://dx.doi.org/10.1107/S1600536810052566
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author Dai, Jing
Chen, Xin-Yuan
author_facet Dai, Jing
Chen, Xin-Yuan
author_sort Dai, Jing
collection PubMed
description In the title compound, [Na(2)(C(6)H(4)N(5)O)(2)(H(2)O)(8)], the Na(I) atom is in a distorted octahedral environment defined by six O atoms, one from the 5-(1-oxopyridin-4-yl)tetra­zolide anion and five from water mol­ecules. Two water mol­ecules act as bridging ligands, resulting in the formation of dimeric units organized around inversion centers. In the organic anion, the pyridine and tetra­zole rings are nearly coplanar, forming a dihedral angle of 4.62 (1)°. The dimeric units and organic anions are connected by O—H⋯O and O—H⋯N hydrogen bonds, leading to the formation of a three-dimensional network.
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spelling pubmed-30504122011-04-26 Di-μ-aqua-bis­{triaqua­[5-(1-oxopyridin-4-yl)tetra­zol-1-ido]sodium} Dai, Jing Chen, Xin-Yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Na(2)(C(6)H(4)N(5)O)(2)(H(2)O)(8)], the Na(I) atom is in a distorted octahedral environment defined by six O atoms, one from the 5-(1-oxopyridin-4-yl)tetra­zolide anion and five from water mol­ecules. Two water mol­ecules act as bridging ligands, resulting in the formation of dimeric units organized around inversion centers. In the organic anion, the pyridine and tetra­zole rings are nearly coplanar, forming a dihedral angle of 4.62 (1)°. The dimeric units and organic anions are connected by O—H⋯O and O—H⋯N hydrogen bonds, leading to the formation of a three-dimensional network. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050412/ /pubmed/21522524 http://dx.doi.org/10.1107/S1600536810052566 Text en © Dai and Chen 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dai, Jing
Chen, Xin-Yuan
Di-μ-aqua-bis­{triaqua­[5-(1-oxopyridin-4-yl)tetra­zol-1-ido]sodium}
title Di-μ-aqua-bis­{triaqua­[5-(1-oxopyridin-4-yl)tetra­zol-1-ido]sodium}
title_full Di-μ-aqua-bis­{triaqua­[5-(1-oxopyridin-4-yl)tetra­zol-1-ido]sodium}
title_fullStr Di-μ-aqua-bis­{triaqua­[5-(1-oxopyridin-4-yl)tetra­zol-1-ido]sodium}
title_full_unstemmed Di-μ-aqua-bis­{triaqua­[5-(1-oxopyridin-4-yl)tetra­zol-1-ido]sodium}
title_short Di-μ-aqua-bis­{triaqua­[5-(1-oxopyridin-4-yl)tetra­zol-1-ido]sodium}
title_sort di-μ-aqua-bis­{triaqua­[5-(1-oxopyridin-4-yl)tetra­zol-1-ido]sodium}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050412/
https://www.ncbi.nlm.nih.gov/pubmed/21522524
http://dx.doi.org/10.1107/S1600536810052566
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