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Di-μ-aqua-bis{triaqua[5-(1-oxopyridin-4-yl)tetrazol-1-ido]sodium}
In the title compound, [Na(2)(C(6)H(4)N(5)O)(2)(H(2)O)(8)], the Na(I) atom is in a distorted octahedral environment defined by six O atoms, one from the 5-(1-oxopyridin-4-yl)tetrazolide anion and five from water molecules. Two water molecules act as bridging ligands, resulting in the formation of...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050412/ https://www.ncbi.nlm.nih.gov/pubmed/21522524 http://dx.doi.org/10.1107/S1600536810052566 |
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author | Dai, Jing Chen, Xin-Yuan |
author_facet | Dai, Jing Chen, Xin-Yuan |
author_sort | Dai, Jing |
collection | PubMed |
description | In the title compound, [Na(2)(C(6)H(4)N(5)O)(2)(H(2)O)(8)], the Na(I) atom is in a distorted octahedral environment defined by six O atoms, one from the 5-(1-oxopyridin-4-yl)tetrazolide anion and five from water molecules. Two water molecules act as bridging ligands, resulting in the formation of dimeric units organized around inversion centers. In the organic anion, the pyridine and tetrazole rings are nearly coplanar, forming a dihedral angle of 4.62 (1)°. The dimeric units and organic anions are connected by O—H⋯O and O—H⋯N hydrogen bonds, leading to the formation of a three-dimensional network. |
format | Text |
id | pubmed-3050412 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30504122011-04-26 Di-μ-aqua-bis{triaqua[5-(1-oxopyridin-4-yl)tetrazol-1-ido]sodium} Dai, Jing Chen, Xin-Yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Na(2)(C(6)H(4)N(5)O)(2)(H(2)O)(8)], the Na(I) atom is in a distorted octahedral environment defined by six O atoms, one from the 5-(1-oxopyridin-4-yl)tetrazolide anion and five from water molecules. Two water molecules act as bridging ligands, resulting in the formation of dimeric units organized around inversion centers. In the organic anion, the pyridine and tetrazole rings are nearly coplanar, forming a dihedral angle of 4.62 (1)°. The dimeric units and organic anions are connected by O—H⋯O and O—H⋯N hydrogen bonds, leading to the formation of a three-dimensional network. International Union of Crystallography 2010-12-24 /pmc/articles/PMC3050412/ /pubmed/21522524 http://dx.doi.org/10.1107/S1600536810052566 Text en © Dai and Chen 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dai, Jing Chen, Xin-Yuan Di-μ-aqua-bis{triaqua[5-(1-oxopyridin-4-yl)tetrazol-1-ido]sodium} |
title | Di-μ-aqua-bis{triaqua[5-(1-oxopyridin-4-yl)tetrazol-1-ido]sodium} |
title_full | Di-μ-aqua-bis{triaqua[5-(1-oxopyridin-4-yl)tetrazol-1-ido]sodium} |
title_fullStr | Di-μ-aqua-bis{triaqua[5-(1-oxopyridin-4-yl)tetrazol-1-ido]sodium} |
title_full_unstemmed | Di-μ-aqua-bis{triaqua[5-(1-oxopyridin-4-yl)tetrazol-1-ido]sodium} |
title_short | Di-μ-aqua-bis{triaqua[5-(1-oxopyridin-4-yl)tetrazol-1-ido]sodium} |
title_sort | di-μ-aqua-bis{triaqua[5-(1-oxopyridin-4-yl)tetrazol-1-ido]sodium} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050412/ https://www.ncbi.nlm.nih.gov/pubmed/21522524 http://dx.doi.org/10.1107/S1600536810052566 |
work_keys_str_mv | AT daijing dimaquabistriaqua51oxopyridin4yltetrazol1idosodium AT chenxinyuan dimaquabistriaqua51oxopyridin4yltetrazol1idosodium |