Bis{(E)-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}copper(II)

In the title mononuclear copper(II) complex, [Cu(C(13)H(10)ClN(2)O(2))(2)], the Cu(II) ion, lying on an inversion center, is four-coordinated in a trans-CuN(2)O(2) square-planar geometry by two phenolate O and two imino N atoms from two symmetry-related N,O-bidentate Schiff base ligands. The shortes...

Descripción completa

Detalles Bibliográficos
Autores principales: Dong, Wen-Kui, Wang, Yuan, Wu, Jian-Chao, Zhang, Shou-Ting
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050418/
https://www.ncbi.nlm.nih.gov/pubmed/21522606
http://dx.doi.org/10.1107/S1600536810052414
Descripción
Sumario:In the title mononuclear copper(II) complex, [Cu(C(13)H(10)ClN(2)O(2))(2)], the Cu(II) ion, lying on an inversion center, is four-coordinated in a trans-CuN(2)O(2) square-planar geometry by two phenolate O and two imino N atoms from two symmetry-related N,O-bidentate Schiff base ligands. The shortest Cu⋯Cu distance is 7.5743 (9) Å. However, there are weak intra­molecular electrostatic inter­actions between the Cu atom and the Cl atom of the ligand, with a Cu⋯Cl distance of 3.3845 (9) Å.

Ejemplares similares