Bis{(E)-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}copper(II)

In the title mononuclear copper(II) complex, [Cu(C(13)H(10)ClN(2)O(2))(2)], the Cu(II) ion, lying on an inversion center, is four-coordinated in a trans-CuN(2)O(2) square-planar geometry by two phenolate O and two imino N atoms from two symmetry-related N,O-bidentate Schiff base ligands. The shortes...

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Detalles Bibliográficos
Autores principales: Dong, Wen-Kui, Wang, Yuan, Wu, Jian-Chao, Zhang, Shou-Ting
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050418/
https://www.ncbi.nlm.nih.gov/pubmed/21522606
http://dx.doi.org/10.1107/S1600536810052414
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author Dong, Wen-Kui
Wang, Yuan
Wu, Jian-Chao
Zhang, Shou-Ting
author_facet Dong, Wen-Kui
Wang, Yuan
Wu, Jian-Chao
Zhang, Shou-Ting
author_sort Dong, Wen-Kui
collection PubMed
description In the title mononuclear copper(II) complex, [Cu(C(13)H(10)ClN(2)O(2))(2)], the Cu(II) ion, lying on an inversion center, is four-coordinated in a trans-CuN(2)O(2) square-planar geometry by two phenolate O and two imino N atoms from two symmetry-related N,O-bidentate Schiff base ligands. The shortest Cu⋯Cu distance is 7.5743 (9) Å. However, there are weak intra­molecular electrostatic inter­actions between the Cu atom and the Cl atom of the ligand, with a Cu⋯Cl distance of 3.3845 (9) Å.
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spelling pubmed-30504182011-04-26 Bis{(E)-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}copper(II) Dong, Wen-Kui Wang, Yuan Wu, Jian-Chao Zhang, Shou-Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear copper(II) complex, [Cu(C(13)H(10)ClN(2)O(2))(2)], the Cu(II) ion, lying on an inversion center, is four-coordinated in a trans-CuN(2)O(2) square-planar geometry by two phenolate O and two imino N atoms from two symmetry-related N,O-bidentate Schiff base ligands. The shortest Cu⋯Cu distance is 7.5743 (9) Å. However, there are weak intra­molecular electrostatic inter­actions between the Cu atom and the Cl atom of the ligand, with a Cu⋯Cl distance of 3.3845 (9) Å. International Union of Crystallography 2010-12-18 /pmc/articles/PMC3050418/ /pubmed/21522606 http://dx.doi.org/10.1107/S1600536810052414 Text en © Dong et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Wen-Kui
Wang, Yuan
Wu, Jian-Chao
Zhang, Shou-Ting
Bis{(E)-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}copper(II)
title Bis{(E)-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}copper(II)
title_full Bis{(E)-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}copper(II)
title_fullStr Bis{(E)-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}copper(II)
title_full_unstemmed Bis{(E)-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}copper(II)
title_short Bis{(E)-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) N,O (1)}copper(II)
title_sort bis{(e)-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]-6-meth­oxy­phenolato-κ(2) n,o (1)}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050418/
https://www.ncbi.nlm.nih.gov/pubmed/21522606
http://dx.doi.org/10.1107/S1600536810052414
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