Dibromidobis[1-(2,4,6-trimethyl­phen­yl)-1,4,5,6-tetra­hydro­pyrimidine-κN (3)]palladium(II)

In the title complex, [PdBr(2)(C(13)H(18)N(2))(2)], the Pd(II) atom is situated on an inversion center. The tetra­hydro­pyrimidine group of the N-(2,4,6-trimethyl­phen­yl)-1,4,5,6-tetra­hydro­pyrimidine ligand is twisted from the square (PdN(2)Br(2)) coordination plane with a C—N—Pd—Br torsion angle...

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Detalles Bibliográficos
Autores principales: Mao, Pu, Liu, Xiujun, Yang, Liangru, Yuan, Jinwei, Song, Maoping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050419/
https://www.ncbi.nlm.nih.gov/pubmed/21522581
http://dx.doi.org/10.1107/S1600536810050968
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author Mao, Pu
Liu, Xiujun
Yang, Liangru
Yuan, Jinwei
Song, Maoping
author_facet Mao, Pu
Liu, Xiujun
Yang, Liangru
Yuan, Jinwei
Song, Maoping
author_sort Mao, Pu
collection PubMed
description In the title complex, [PdBr(2)(C(13)H(18)N(2))(2)], the Pd(II) atom is situated on an inversion center. The tetra­hydro­pyrimidine group of the N-(2,4,6-trimethyl­phen­yl)-1,4,5,6-tetra­hydro­pyrimidine ligand is twisted from the square (PdN(2)Br(2)) coordination plane with a C—N—Pd—Br torsion angle of 81.8 (4)°; this is different from the angle of 43.47 (14)°, reported in a closely related structure, dichloridobis(1-methyl-1,4,5,6-tetra­hydro­pyrimidine)­palladium(II).
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spelling pubmed-30504192011-04-26 Dibromidobis[1-(2,4,6-trimethyl­phen­yl)-1,4,5,6-tetra­hydro­pyrimidine-κN (3)]palladium(II) Mao, Pu Liu, Xiujun Yang, Liangru Yuan, Jinwei Song, Maoping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PdBr(2)(C(13)H(18)N(2))(2)], the Pd(II) atom is situated on an inversion center. The tetra­hydro­pyrimidine group of the N-(2,4,6-trimethyl­phen­yl)-1,4,5,6-tetra­hydro­pyrimidine ligand is twisted from the square (PdN(2)Br(2)) coordination plane with a C—N—Pd—Br torsion angle of 81.8 (4)°; this is different from the angle of 43.47 (14)°, reported in a closely related structure, dichloridobis(1-methyl-1,4,5,6-tetra­hydro­pyrimidine)­palladium(II). International Union of Crystallography 2010-12-11 /pmc/articles/PMC3050419/ /pubmed/21522581 http://dx.doi.org/10.1107/S1600536810050968 Text en © Mao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mao, Pu
Liu, Xiujun
Yang, Liangru
Yuan, Jinwei
Song, Maoping
Dibromidobis[1-(2,4,6-trimethyl­phen­yl)-1,4,5,6-tetra­hydro­pyrimidine-κN (3)]palladium(II)
title Dibromidobis[1-(2,4,6-trimethyl­phen­yl)-1,4,5,6-tetra­hydro­pyrimidine-κN (3)]palladium(II)
title_full Dibromidobis[1-(2,4,6-trimethyl­phen­yl)-1,4,5,6-tetra­hydro­pyrimidine-κN (3)]palladium(II)
title_fullStr Dibromidobis[1-(2,4,6-trimethyl­phen­yl)-1,4,5,6-tetra­hydro­pyrimidine-κN (3)]palladium(II)
title_full_unstemmed Dibromidobis[1-(2,4,6-trimethyl­phen­yl)-1,4,5,6-tetra­hydro­pyrimidine-κN (3)]palladium(II)
title_short Dibromidobis[1-(2,4,6-trimethyl­phen­yl)-1,4,5,6-tetra­hydro­pyrimidine-κN (3)]palladium(II)
title_sort dibromidobis[1-(2,4,6-trimethyl­phen­yl)-1,4,5,6-tetra­hydro­pyrimidine-κn (3)]palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050419/
https://www.ncbi.nlm.nih.gov/pubmed/21522581
http://dx.doi.org/10.1107/S1600536810050968
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AT yuanjinwei dibromidobis1246trimethylphenyl1456tetrahydropyrimidinekn3palladiumii
AT songmaoping dibromidobis1246trimethylphenyl1456tetrahydropyrimidinekn3palladiumii

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