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Bis(tetrabutylammonium) bis(3,4,5-trioxocyclopent-1-ene-1,2-dithiolato-κ(2) S,S′)cadmate(II) 0.25-hydrate
The title compound, (C(16)H(36)N)(2)[Cd(C(5)O(3)S(2))(2)]·0.25H(2)O, contains two disordered tetrabutylammonium cations, a complex [Cd(C(5)O(3)S(2))(2)](2−) anion and a 0.25-hydrate water. The anion is composed of a bidentate coordinated 3,4,5-trioxocyclopent-1-ene-1,2-dithiolate (dtcroc) group...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050421/ https://www.ncbi.nlm.nih.gov/pubmed/21522531 http://dx.doi.org/10.1107/S1600536810049913 |
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author | Chen, Hong-Yu Xia, Guang-Ming Zhang, Zhen-Wei Li, Ping |
author_facet | Chen, Hong-Yu Xia, Guang-Ming Zhang, Zhen-Wei Li, Ping |
author_sort | Chen, Hong-Yu |
collection | PubMed |
description | The title compound, (C(16)H(36)N)(2)[Cd(C(5)O(3)S(2))(2)]·0.25H(2)O, contains two disordered tetrabutylammonium cations, a complex [Cd(C(5)O(3)S(2))(2)](2−) anion and a 0.25-hydrate water. The anion is composed of a bidentate coordinated 3,4,5-trioxocyclopent-1-ene-1,2-dithiolate (dtcroc) group forming a distorted tetrahedral configuration around the Cd(II) ion. The dihedral angle between the least-squares planes of the ten-atom sulfur-substituted croconate groups in the anion is 84.10 (8)°. The crystal packing is stabilized by weak C—H⋯O and C—H⋯S cation–anion hydrogen-bond interactions. In each of the two cations one butyl group is disordered over two positions in the ratios 0.589 (11):0.411 (11) and 0.796 (12):0.204 (12). |
format | Text |
id | pubmed-3050421 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30504212011-04-26 Bis(tetrabutylammonium) bis(3,4,5-trioxocyclopent-1-ene-1,2-dithiolato-κ(2) S,S′)cadmate(II) 0.25-hydrate Chen, Hong-Yu Xia, Guang-Ming Zhang, Zhen-Wei Li, Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(16)H(36)N)(2)[Cd(C(5)O(3)S(2))(2)]·0.25H(2)O, contains two disordered tetrabutylammonium cations, a complex [Cd(C(5)O(3)S(2))(2)](2−) anion and a 0.25-hydrate water. The anion is composed of a bidentate coordinated 3,4,5-trioxocyclopent-1-ene-1,2-dithiolate (dtcroc) group forming a distorted tetrahedral configuration around the Cd(II) ion. The dihedral angle between the least-squares planes of the ten-atom sulfur-substituted croconate groups in the anion is 84.10 (8)°. The crystal packing is stabilized by weak C—H⋯O and C—H⋯S cation–anion hydrogen-bond interactions. In each of the two cations one butyl group is disordered over two positions in the ratios 0.589 (11):0.411 (11) and 0.796 (12):0.204 (12). International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050421/ /pubmed/21522531 http://dx.doi.org/10.1107/S1600536810049913 Text en © Chen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Hong-Yu Xia, Guang-Ming Zhang, Zhen-Wei Li, Ping Bis(tetrabutylammonium) bis(3,4,5-trioxocyclopent-1-ene-1,2-dithiolato-κ(2) S,S′)cadmate(II) 0.25-hydrate |
title | Bis(tetrabutylammonium) bis(3,4,5-trioxocyclopent-1-ene-1,2-dithiolato-κ(2)
S,S′)cadmate(II) 0.25-hydrate |
title_full | Bis(tetrabutylammonium) bis(3,4,5-trioxocyclopent-1-ene-1,2-dithiolato-κ(2)
S,S′)cadmate(II) 0.25-hydrate |
title_fullStr | Bis(tetrabutylammonium) bis(3,4,5-trioxocyclopent-1-ene-1,2-dithiolato-κ(2)
S,S′)cadmate(II) 0.25-hydrate |
title_full_unstemmed | Bis(tetrabutylammonium) bis(3,4,5-trioxocyclopent-1-ene-1,2-dithiolato-κ(2)
S,S′)cadmate(II) 0.25-hydrate |
title_short | Bis(tetrabutylammonium) bis(3,4,5-trioxocyclopent-1-ene-1,2-dithiolato-κ(2)
S,S′)cadmate(II) 0.25-hydrate |
title_sort | bis(tetrabutylammonium) bis(3,4,5-trioxocyclopent-1-ene-1,2-dithiolato-κ(2)
s,s′)cadmate(ii) 0.25-hydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050421/ https://www.ncbi.nlm.nih.gov/pubmed/21522531 http://dx.doi.org/10.1107/S1600536810049913 |
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