Bis(tetra­butyl­ammonium) bis­(3,4,5-trioxocyclo­pent-1-ene-1,2-dithiol­ato-κ(2) S,S′)cadmate(II) 0.25-hydrate

The title compound, (C(16)H(36)N)(2)[Cd(C(5)O(3)S(2))(2)]·0.25H(2)O, contains two disordered tetra­butyl­ammonium cations, a complex [Cd(C(5)O(3)S(2))(2)](2−) anion and a 0.25-hydrate water. The anion is composed of a bidentate coordinated 3,4,5-trioxocyclo­pent-1-ene-1,2-dithiol­ate (dtcroc) group...

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Detalles Bibliográficos
Autores principales: Chen, Hong-Yu, Xia, Guang-Ming, Zhang, Zhen-Wei, Li, Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050421/
https://www.ncbi.nlm.nih.gov/pubmed/21522531
http://dx.doi.org/10.1107/S1600536810049913
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author Chen, Hong-Yu
Xia, Guang-Ming
Zhang, Zhen-Wei
Li, Ping
author_facet Chen, Hong-Yu
Xia, Guang-Ming
Zhang, Zhen-Wei
Li, Ping
author_sort Chen, Hong-Yu
collection PubMed
description The title compound, (C(16)H(36)N)(2)[Cd(C(5)O(3)S(2))(2)]·0.25H(2)O, contains two disordered tetra­butyl­ammonium cations, a complex [Cd(C(5)O(3)S(2))(2)](2−) anion and a 0.25-hydrate water. The anion is composed of a bidentate coordinated 3,4,5-trioxocyclo­pent-1-ene-1,2-dithiol­ate (dtcroc) group forming a distorted tetra­hedral configuration around the Cd(II) ion. The dihedral angle between the least-squares planes of the ten-atom sulfur-substituted croconate groups in the anion is 84.10 (8)°. The crystal packing is stabilized by weak C—H⋯O and C—H⋯S cation–anion hydrogen-bond inter­actions. In each of the two cations one butyl group is disordered over two positions in the ratios 0.589 (11):0.411 (11) and 0.796 (12):0.204 (12).
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spelling pubmed-30504212011-04-26 Bis(tetra­butyl­ammonium) bis­(3,4,5-trioxocyclo­pent-1-ene-1,2-dithiol­ato-κ(2) S,S′)cadmate(II) 0.25-hydrate Chen, Hong-Yu Xia, Guang-Ming Zhang, Zhen-Wei Li, Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(16)H(36)N)(2)[Cd(C(5)O(3)S(2))(2)]·0.25H(2)O, contains two disordered tetra­butyl­ammonium cations, a complex [Cd(C(5)O(3)S(2))(2)](2−) anion and a 0.25-hydrate water. The anion is composed of a bidentate coordinated 3,4,5-trioxocyclo­pent-1-ene-1,2-dithiol­ate (dtcroc) group forming a distorted tetra­hedral configuration around the Cd(II) ion. The dihedral angle between the least-squares planes of the ten-atom sulfur-substituted croconate groups in the anion is 84.10 (8)°. The crystal packing is stabilized by weak C—H⋯O and C—H⋯S cation–anion hydrogen-bond inter­actions. In each of the two cations one butyl group is disordered over two positions in the ratios 0.589 (11):0.411 (11) and 0.796 (12):0.204 (12). International Union of Crystallography 2010-12-04 /pmc/articles/PMC3050421/ /pubmed/21522531 http://dx.doi.org/10.1107/S1600536810049913 Text en © Chen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Hong-Yu
Xia, Guang-Ming
Zhang, Zhen-Wei
Li, Ping
Bis(tetra­butyl­ammonium) bis­(3,4,5-trioxocyclo­pent-1-ene-1,2-dithiol­ato-κ(2) S,S′)cadmate(II) 0.25-hydrate
title Bis(tetra­butyl­ammonium) bis­(3,4,5-trioxocyclo­pent-1-ene-1,2-dithiol­ato-κ(2) S,S′)cadmate(II) 0.25-hydrate
title_full Bis(tetra­butyl­ammonium) bis­(3,4,5-trioxocyclo­pent-1-ene-1,2-dithiol­ato-κ(2) S,S′)cadmate(II) 0.25-hydrate
title_fullStr Bis(tetra­butyl­ammonium) bis­(3,4,5-trioxocyclo­pent-1-ene-1,2-dithiol­ato-κ(2) S,S′)cadmate(II) 0.25-hydrate
title_full_unstemmed Bis(tetra­butyl­ammonium) bis­(3,4,5-trioxocyclo­pent-1-ene-1,2-dithiol­ato-κ(2) S,S′)cadmate(II) 0.25-hydrate
title_short Bis(tetra­butyl­ammonium) bis­(3,4,5-trioxocyclo­pent-1-ene-1,2-dithiol­ato-κ(2) S,S′)cadmate(II) 0.25-hydrate
title_sort bis(tetra­butyl­ammonium) bis­(3,4,5-trioxocyclo­pent-1-ene-1,2-dithiol­ato-κ(2) s,s′)cadmate(ii) 0.25-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050421/
https://www.ncbi.nlm.nih.gov/pubmed/21522531
http://dx.doi.org/10.1107/S1600536810049913
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