Diaqua­[3,5-bis­(4-pyrid­yl)-1H-1,2,4-triazole-κN (3)](pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))nickel(II)

In the title compound, [Ni(C(7)H(3)NO(4))(C(12)H(9)N(5))(H(2)O)(2)], the Ni(II) atom is coordinated in a distorted octa­hedral geometry by one N and two O atoms from a pyridine-2,6-dicarboxyl­ate ligand, one N atom from a 3,5-bis­(4-pyrid­yl)-1H-1,2,4-triazole ligand in equatorial positions and two...

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Detalles Bibliográficos
Autores principales: Cheng, Feng-Jie, Wang, Yi-Sen, Liu, Yan-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051425/
https://www.ncbi.nlm.nih.gov/pubmed/21522823
http://dx.doi.org/10.1107/S1600536810053687
Descripción
Sumario:In the title compound, [Ni(C(7)H(3)NO(4))(C(12)H(9)N(5))(H(2)O)(2)], the Ni(II) atom is coordinated in a distorted octa­hedral geometry by one N and two O atoms from a pyridine-2,6-dicarboxyl­ate ligand, one N atom from a 3,5-bis­(4-pyrid­yl)-1H-1,2,4-triazole ligand in equatorial positions and two water mol­ecules in axial positions. The crystal packing is consolidated by inter­molecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds.

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