Tetra­kis(benzyl­amino)­phospho­nium chloride

The title salt, [P(NHCH(2)C(6)H(5))(4)](+)·Cl(−), crystallizes with the P atom and Cl(−) anion lying on a twofold rotation axis. The P atom has a slightly distorted tetra­hedral geometry with two classes of N—P—N angles [101.15 (10) and 100.55 (11)° and 113.07 (9) and 114.83 (8)°] and the environmen...

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Detalles Bibliográficos
Autores principales: Gholivand, Khodayar, Mostaanzadeh, Hossein, Farshadian, Sedigheh
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051427/
https://www.ncbi.nlm.nih.gov/pubmed/21522999
http://dx.doi.org/10.1107/S1600536810054401
Descripción
Sumario:The title salt, [P(NHCH(2)C(6)H(5))(4)](+)·Cl(−), crystallizes with the P atom and Cl(−) anion lying on a twofold rotation axis. The P atom has a slightly distorted tetra­hedral geometry with two classes of N—P—N angles [101.15 (10) and 100.55 (11)° and 113.07 (9) and 114.83 (8)°] and the environments of sp (2)-hybridized N atoms are essentially planar (sum of angles = 359.9 and 360.1°). In the crystal, the phospho­nium ion inter­acts with each neighboring chloride ion via two approximately equal N—H⋯Cl inter­actions, forming parallel chains along the c axis.

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