Tetra­kis{4-[(2H-tetra­zol-5-yl)meth­yl]morpholin-4-ium} dodeca­tungstosilicate hexa­hydrate

The crystal structure of the title compound, (C(6)H(12)N(5)O)(4)[W(12)(SiO(4))O(36)]·6H(2)O, consists of an α-Keggin-type [W(12)(SiO(4))O(36)](4−) polyoxidoanion, four [(2H-tetra­zol-5-yl)meth­yl]morpholinium cations and six uncoordinated water mol­ecules. In the cations, the morpholine rings displa...

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Detalles Bibliográficos
Autores principales: Yousefi, Mohammad, Eshtiagh-Hosseini, Hossein, Mirzaei, Masoud, Gholizadeh, Ahmad, Nikpour, Mohsen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051431/
https://www.ncbi.nlm.nih.gov/pubmed/21522920
http://dx.doi.org/10.1107/S1600536811001772
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author Yousefi, Mohammad
Eshtiagh-Hosseini, Hossein
Mirzaei, Masoud
Gholizadeh, Ahmad
Nikpour, Mohsen
author_facet Yousefi, Mohammad
Eshtiagh-Hosseini, Hossein
Mirzaei, Masoud
Gholizadeh, Ahmad
Nikpour, Mohsen
author_sort Yousefi, Mohammad
collection PubMed
description The crystal structure of the title compound, (C(6)H(12)N(5)O)(4)[W(12)(SiO(4))O(36)]·6H(2)O, consists of an α-Keggin-type [W(12)(SiO(4))O(36)](4−) polyoxidoanion, four [(2H-tetra­zol-5-yl)meth­yl]morpholinium cations and six uncoordinated water mol­ecules. In the cations, the morpholine rings display chair conformations. Extensive N—H⋯O, N—H⋯N, O—H⋯O and O—H⋯N hydrogen bonds are present in the crystal structure.
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spelling pubmed-30514312011-04-26 Tetra­kis{4-[(2H-tetra­zol-5-yl)meth­yl]morpholin-4-ium} dodeca­tungstosilicate hexa­hydrate Yousefi, Mohammad Eshtiagh-Hosseini, Hossein Mirzaei, Masoud Gholizadeh, Ahmad Nikpour, Mohsen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, (C(6)H(12)N(5)O)(4)[W(12)(SiO(4))O(36)]·6H(2)O, consists of an α-Keggin-type [W(12)(SiO(4))O(36)](4−) polyoxidoanion, four [(2H-tetra­zol-5-yl)meth­yl]morpholinium cations and six uncoordinated water mol­ecules. In the cations, the morpholine rings display chair conformations. Extensive N—H⋯O, N—H⋯N, O—H⋯O and O—H⋯N hydrogen bonds are present in the crystal structure. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051431/ /pubmed/21522920 http://dx.doi.org/10.1107/S1600536811001772 Text en © Yousefi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yousefi, Mohammad
Eshtiagh-Hosseini, Hossein
Mirzaei, Masoud
Gholizadeh, Ahmad
Nikpour, Mohsen
Tetra­kis{4-[(2H-tetra­zol-5-yl)meth­yl]morpholin-4-ium} dodeca­tungstosilicate hexa­hydrate
title Tetra­kis{4-[(2H-tetra­zol-5-yl)meth­yl]morpholin-4-ium} dodeca­tungstosilicate hexa­hydrate
title_full Tetra­kis{4-[(2H-tetra­zol-5-yl)meth­yl]morpholin-4-ium} dodeca­tungstosilicate hexa­hydrate
title_fullStr Tetra­kis{4-[(2H-tetra­zol-5-yl)meth­yl]morpholin-4-ium} dodeca­tungstosilicate hexa­hydrate
title_full_unstemmed Tetra­kis{4-[(2H-tetra­zol-5-yl)meth­yl]morpholin-4-ium} dodeca­tungstosilicate hexa­hydrate
title_short Tetra­kis{4-[(2H-tetra­zol-5-yl)meth­yl]morpholin-4-ium} dodeca­tungstosilicate hexa­hydrate
title_sort tetra­kis{4-[(2h-tetra­zol-5-yl)meth­yl]morpholin-4-ium} dodeca­tungstosilicate hexa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051431/
https://www.ncbi.nlm.nih.gov/pubmed/21522920
http://dx.doi.org/10.1107/S1600536811001772
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