Bis(μ-3,5-difluorobenzoato)bis[(3,5-di­fluorobenzoato)dimethyltin(IV)]

In the dinuclear title complex, [Sn(2)(CH(3))(4)(C(7)H(3)F(2)O(2))(4)], the Sn(IV) atom is chelated by two 3,5-difluoro­benzoate (dfb) anions and coordinated by two methyl groups while an O atom from the adjacent dfb anion bridges the Sb atom with a longer Sb—O bond distance of 2.793 (4) Å. The comp...

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Detalles Bibliográficos
Autores principales: Liu, Hong, Yin, Han-Dong, Li, Jing, Wang, Da-Qi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051437/
https://www.ncbi.nlm.nih.gov/pubmed/21522832
http://dx.doi.org/10.1107/S1600536810054061
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author Liu, Hong
Yin, Han-Dong
Li, Jing
Wang, Da-Qi
author_facet Liu, Hong
Yin, Han-Dong
Li, Jing
Wang, Da-Qi
author_sort Liu, Hong
collection PubMed
description In the dinuclear title complex, [Sn(2)(CH(3))(4)(C(7)H(3)F(2)O(2))(4)], the Sn(IV) atom is chelated by two 3,5-difluoro­benzoate (dfb) anions and coordinated by two methyl groups while an O atom from the adjacent dfb anion bridges the Sb atom with a longer Sb—O bond distance of 2.793 (4) Å. The complex mol­ecule has 2 symmetry and the Sn(IV) atom is in a distorted penta­gonal–bipyramidal coordination geometry. In the crystal, mol­ecules are connected by C—H⋯O and C—H⋯F hydrogen bonds.
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spelling pubmed-30514372011-04-26 Bis(μ-3,5-difluorobenzoato)bis[(3,5-di­fluorobenzoato)dimethyltin(IV)] Liu, Hong Yin, Han-Dong Li, Jing Wang, Da-Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the dinuclear title complex, [Sn(2)(CH(3))(4)(C(7)H(3)F(2)O(2))(4)], the Sn(IV) atom is chelated by two 3,5-difluoro­benzoate (dfb) anions and coordinated by two methyl groups while an O atom from the adjacent dfb anion bridges the Sb atom with a longer Sb—O bond distance of 2.793 (4) Å. The complex mol­ecule has 2 symmetry and the Sn(IV) atom is in a distorted penta­gonal–bipyramidal coordination geometry. In the crystal, mol­ecules are connected by C—H⋯O and C—H⋯F hydrogen bonds. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051437/ /pubmed/21522832 http://dx.doi.org/10.1107/S1600536810054061 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Hong
Yin, Han-Dong
Li, Jing
Wang, Da-Qi
Bis(μ-3,5-difluorobenzoato)bis[(3,5-di­fluorobenzoato)dimethyltin(IV)]
title Bis(μ-3,5-difluorobenzoato)bis[(3,5-di­fluorobenzoato)dimethyltin(IV)]
title_full Bis(μ-3,5-difluorobenzoato)bis[(3,5-di­fluorobenzoato)dimethyltin(IV)]
title_fullStr Bis(μ-3,5-difluorobenzoato)bis[(3,5-di­fluorobenzoato)dimethyltin(IV)]
title_full_unstemmed Bis(μ-3,5-difluorobenzoato)bis[(3,5-di­fluorobenzoato)dimethyltin(IV)]
title_short Bis(μ-3,5-difluorobenzoato)bis[(3,5-di­fluorobenzoato)dimethyltin(IV)]
title_sort bis(μ-3,5-difluorobenzoato)bis[(3,5-di­fluorobenzoato)dimethyltin(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051437/
https://www.ncbi.nlm.nih.gov/pubmed/21522832
http://dx.doi.org/10.1107/S1600536810054061
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