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Di-μ(2)-methano­lato-bis­(μ-4-methyl-5-sulfanyl­idene-4,5-dihydro-1H-1,2,4-triazolido-κ(2) N (1):N (2))di-μ(3)-oxido-tetra­kis­[dimethyl­tin(IV)]

The title distannoxane, [Sn(4)(CH(3))(8)(C(3)H(4)N(3)S)(2)(CH(3)O)(2)O(2)], lies about a center of inversion; the tetra­nuclear mol­ecule features a three-rung-staircase Sn(4)O(4) core in which the two crystallographically independent Sn(IV) atoms are bridged by the triazolide group. The negatively...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051439/
https://www.ncbi.nlm.nih.gov/pubmed/21522897
http://dx.doi.org/10.1107/S1600536811001905
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author Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Najafi, Ezzatollah
collection PubMed
description The title distannoxane, [Sn(4)(CH(3))(8)(C(3)H(4)N(3)S)(2)(CH(3)O)(2)O(2)], lies about a center of inversion; the tetra­nuclear mol­ecule features a three-rung-staircase Sn(4)O(4) core in which the two crystallographically independent Sn(IV) atoms are bridged by the triazolide group. The negatively charged N atom of the triazolide group binds to the terminal Sn atom at a shorter distance [Sn—N = 2.239 (2) Å] compared with the neutral N atom that binds to the central Sn atom [Sn← N = 2.757 (3) Å]. The oxide O atom is three-coordinate whereas the methano­late O atom is two-coordinate. The terminal Sn atom is five-coordinate in a cis-C(3)SnNO trigonal–bipyramidal environment, whereas the central Sn atom is six-coordinate in a C(2)SnNO(3) skew-trapezoidal–bipyramidal geometry.
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spelling pubmed-30514392011-04-26 Di-μ(2)-methano­lato-bis­(μ-4-methyl-5-sulfanyl­idene-4,5-dihydro-1H-1,2,4-triazolido-κ(2) N (1):N (2))di-μ(3)-oxido-tetra­kis­[dimethyl­tin(IV)] Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title distannoxane, [Sn(4)(CH(3))(8)(C(3)H(4)N(3)S)(2)(CH(3)O)(2)O(2)], lies about a center of inversion; the tetra­nuclear mol­ecule features a three-rung-staircase Sn(4)O(4) core in which the two crystallographically independent Sn(IV) atoms are bridged by the triazolide group. The negatively charged N atom of the triazolide group binds to the terminal Sn atom at a shorter distance [Sn—N = 2.239 (2) Å] compared with the neutral N atom that binds to the central Sn atom [Sn← N = 2.757 (3) Å]. The oxide O atom is three-coordinate whereas the methano­late O atom is two-coordinate. The terminal Sn atom is five-coordinate in a cis-C(3)SnNO trigonal–bipyramidal environment, whereas the central Sn atom is six-coordinate in a C(2)SnNO(3) skew-trapezoidal–bipyramidal geometry. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051439/ /pubmed/21522897 http://dx.doi.org/10.1107/S1600536811001905 Text en © Najafi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
Di-μ(2)-methano­lato-bis­(μ-4-methyl-5-sulfanyl­idene-4,5-dihydro-1H-1,2,4-triazolido-κ(2) N (1):N (2))di-μ(3)-oxido-tetra­kis­[dimethyl­tin(IV)]
title Di-μ(2)-methano­lato-bis­(μ-4-methyl-5-sulfanyl­idene-4,5-dihydro-1H-1,2,4-triazolido-κ(2) N (1):N (2))di-μ(3)-oxido-tetra­kis­[dimethyl­tin(IV)]
title_full Di-μ(2)-methano­lato-bis­(μ-4-methyl-5-sulfanyl­idene-4,5-dihydro-1H-1,2,4-triazolido-κ(2) N (1):N (2))di-μ(3)-oxido-tetra­kis­[dimethyl­tin(IV)]
title_fullStr Di-μ(2)-methano­lato-bis­(μ-4-methyl-5-sulfanyl­idene-4,5-dihydro-1H-1,2,4-triazolido-κ(2) N (1):N (2))di-μ(3)-oxido-tetra­kis­[dimethyl­tin(IV)]
title_full_unstemmed Di-μ(2)-methano­lato-bis­(μ-4-methyl-5-sulfanyl­idene-4,5-dihydro-1H-1,2,4-triazolido-κ(2) N (1):N (2))di-μ(3)-oxido-tetra­kis­[dimethyl­tin(IV)]
title_short Di-μ(2)-methano­lato-bis­(μ-4-methyl-5-sulfanyl­idene-4,5-dihydro-1H-1,2,4-triazolido-κ(2) N (1):N (2))di-μ(3)-oxido-tetra­kis­[dimethyl­tin(IV)]
title_sort di-μ(2)-methano­lato-bis­(μ-4-methyl-5-sulfanyl­idene-4,5-dihydro-1h-1,2,4-triazolido-κ(2) n (1):n (2))di-μ(3)-oxido-tetra­kis­[dimethyl­tin(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051439/
https://www.ncbi.nlm.nih.gov/pubmed/21522897
http://dx.doi.org/10.1107/S1600536811001905
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