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Di-μ(2)-methanolato-bis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazolido-κ(2) N (1):N (2))di-μ(3)-oxido-tetrakis[dimethyltin(IV)]
The title distannoxane, [Sn(4)(CH(3))(8)(C(3)H(4)N(3)S)(2)(CH(3)O)(2)O(2)], lies about a center of inversion; the tetranuclear molecule features a three-rung-staircase Sn(4)O(4) core in which the two crystallographically independent Sn(IV) atoms are bridged by the triazolide group. The negatively...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051439/ https://www.ncbi.nlm.nih.gov/pubmed/21522897 http://dx.doi.org/10.1107/S1600536811001905 |
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author | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
author_facet | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
author_sort | Najafi, Ezzatollah |
collection | PubMed |
description | The title distannoxane, [Sn(4)(CH(3))(8)(C(3)H(4)N(3)S)(2)(CH(3)O)(2)O(2)], lies about a center of inversion; the tetranuclear molecule features a three-rung-staircase Sn(4)O(4) core in which the two crystallographically independent Sn(IV) atoms are bridged by the triazolide group. The negatively charged N atom of the triazolide group binds to the terminal Sn atom at a shorter distance [Sn—N = 2.239 (2) Å] compared with the neutral N atom that binds to the central Sn atom [Sn← N = 2.757 (3) Å]. The oxide O atom is three-coordinate whereas the methanolate O atom is two-coordinate. The terminal Sn atom is five-coordinate in a cis-C(3)SnNO trigonal–bipyramidal environment, whereas the central Sn atom is six-coordinate in a C(2)SnNO(3) skew-trapezoidal–bipyramidal geometry. |
format | Text |
id | pubmed-3051439 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30514392011-04-26 Di-μ(2)-methanolato-bis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazolido-κ(2) N (1):N (2))di-μ(3)-oxido-tetrakis[dimethyltin(IV)] Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title distannoxane, [Sn(4)(CH(3))(8)(C(3)H(4)N(3)S)(2)(CH(3)O)(2)O(2)], lies about a center of inversion; the tetranuclear molecule features a three-rung-staircase Sn(4)O(4) core in which the two crystallographically independent Sn(IV) atoms are bridged by the triazolide group. The negatively charged N atom of the triazolide group binds to the terminal Sn atom at a shorter distance [Sn—N = 2.239 (2) Å] compared with the neutral N atom that binds to the central Sn atom [Sn← N = 2.757 (3) Å]. The oxide O atom is three-coordinate whereas the methanolate O atom is two-coordinate. The terminal Sn atom is five-coordinate in a cis-C(3)SnNO trigonal–bipyramidal environment, whereas the central Sn atom is six-coordinate in a C(2)SnNO(3) skew-trapezoidal–bipyramidal geometry. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051439/ /pubmed/21522897 http://dx.doi.org/10.1107/S1600536811001905 Text en © Najafi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Di-μ(2)-methanolato-bis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazolido-κ(2) N (1):N (2))di-μ(3)-oxido-tetrakis[dimethyltin(IV)] |
title | Di-μ(2)-methanolato-bis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazolido-κ(2)
N
(1):N
(2))di-μ(3)-oxido-tetrakis[dimethyltin(IV)] |
title_full | Di-μ(2)-methanolato-bis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazolido-κ(2)
N
(1):N
(2))di-μ(3)-oxido-tetrakis[dimethyltin(IV)] |
title_fullStr | Di-μ(2)-methanolato-bis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazolido-κ(2)
N
(1):N
(2))di-μ(3)-oxido-tetrakis[dimethyltin(IV)] |
title_full_unstemmed | Di-μ(2)-methanolato-bis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazolido-κ(2)
N
(1):N
(2))di-μ(3)-oxido-tetrakis[dimethyltin(IV)] |
title_short | Di-μ(2)-methanolato-bis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1H-1,2,4-triazolido-κ(2)
N
(1):N
(2))di-μ(3)-oxido-tetrakis[dimethyltin(IV)] |
title_sort | di-μ(2)-methanolato-bis(μ-4-methyl-5-sulfanylidene-4,5-dihydro-1h-1,2,4-triazolido-κ(2)
n
(1):n
(2))di-μ(3)-oxido-tetrakis[dimethyltin(iv)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051439/ https://www.ncbi.nlm.nih.gov/pubmed/21522897 http://dx.doi.org/10.1107/S1600536811001905 |
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