3-Meth­oxy­carbonyl-1-methyl­pyrazinium tetra­chlorido(pyrazine-2-carboxyl­ato-κ(2) N (1),O)stannate(IV)

In the reaction of pyrazine-2-carb­oxy­lic acid and stannic chloride in methanol, one equivalent of the carb­oxy­lic acid is methyl­ated at the 4-amino site and is also esterified, yielding the title salt, (C(7)H(9)N(2)O(2))[SnCl(4)(C(5)H(3)N(2)O(2))]. The Sn(IV) atom in the anion is N,O-chelated by...

Descripción completa

Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051442/
https://www.ncbi.nlm.nih.gov/pubmed/21522893
http://dx.doi.org/10.1107/S1600536811001929
_version_ 1782199479945920512
author Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Najafi, Ezzatollah
collection PubMed
description In the reaction of pyrazine-2-carb­oxy­lic acid and stannic chloride in methanol, one equivalent of the carb­oxy­lic acid is methyl­ated at the 4-amino site and is also esterified, yielding the title salt, (C(7)H(9)N(2)O(2))[SnCl(4)(C(5)H(3)N(2)O(2))]. The Sn(IV) atom in the anion is N,O-chelated by a pyrazine-2-carboxyl­ate in a cis-SnNOCl(4) octa­hedral geometry.
format Text
id pubmed-3051442
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30514422011-04-26 3-Meth­oxy­carbonyl-1-methyl­pyrazinium tetra­chlorido(pyrazine-2-carboxyl­ato-κ(2) N (1),O)stannate(IV) Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the reaction of pyrazine-2-carb­oxy­lic acid and stannic chloride in methanol, one equivalent of the carb­oxy­lic acid is methyl­ated at the 4-amino site and is also esterified, yielding the title salt, (C(7)H(9)N(2)O(2))[SnCl(4)(C(5)H(3)N(2)O(2))]. The Sn(IV) atom in the anion is N,O-chelated by a pyrazine-2-carboxyl­ate in a cis-SnNOCl(4) octa­hedral geometry. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051442/ /pubmed/21522893 http://dx.doi.org/10.1107/S1600536811001929 Text en © Najafi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
3-Meth­oxy­carbonyl-1-methyl­pyrazinium tetra­chlorido(pyrazine-2-carboxyl­ato-κ(2) N (1),O)stannate(IV)
title 3-Meth­oxy­carbonyl-1-methyl­pyrazinium tetra­chlorido(pyrazine-2-carboxyl­ato-κ(2) N (1),O)stannate(IV)
title_full 3-Meth­oxy­carbonyl-1-methyl­pyrazinium tetra­chlorido(pyrazine-2-carboxyl­ato-κ(2) N (1),O)stannate(IV)
title_fullStr 3-Meth­oxy­carbonyl-1-methyl­pyrazinium tetra­chlorido(pyrazine-2-carboxyl­ato-κ(2) N (1),O)stannate(IV)
title_full_unstemmed 3-Meth­oxy­carbonyl-1-methyl­pyrazinium tetra­chlorido(pyrazine-2-carboxyl­ato-κ(2) N (1),O)stannate(IV)
title_short 3-Meth­oxy­carbonyl-1-methyl­pyrazinium tetra­chlorido(pyrazine-2-carboxyl­ato-κ(2) N (1),O)stannate(IV)
title_sort 3-meth­oxy­carbonyl-1-methyl­pyrazinium tetra­chlorido(pyrazine-2-carboxyl­ato-κ(2) n (1),o)stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051442/
https://www.ncbi.nlm.nih.gov/pubmed/21522893
http://dx.doi.org/10.1107/S1600536811001929
work_keys_str_mv AT najafiezzatollah 3methoxycarbonyl1methylpyraziniumtetrachloridopyrazine2carboxylatok2n1ostannateiv
AT aminimostafam 3methoxycarbonyl1methylpyraziniumtetrachloridopyrazine2carboxylatok2n1ostannateiv
AT ngseikweng 3methoxycarbonyl1methylpyraziniumtetrachloridopyrazine2carboxylatok2n1ostannateiv

Ejemplares similares