Trisilver(I) citrate

Trisilver(I) citrate, 3Ag(+)·C(6)H(5)O(7) (3−), was obtained by evaporation of a saturated aqueous solution of the raw material that had been obtained from sodium dihydrogen citrate and silver nitrate. It features one formula unit in the asymmetric unit. There is an intra­molecular O—H⋯O hydrogen bo...

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Detalles Bibliográficos
Autor principal: Fischer, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051445/
https://www.ncbi.nlm.nih.gov/pubmed/21522908
http://dx.doi.org/10.1107/S160053681100239X
Descripción
Sumario:Trisilver(I) citrate, 3Ag(+)·C(6)H(5)O(7) (3−), was obtained by evaporation of a saturated aqueous solution of the raw material that had been obtained from sodium dihydrogen citrate and silver nitrate. It features one formula unit in the asymmetric unit. There is an intra­molecular O—H⋯O hydrogen bond between the OH group and one of the terminal carboxyl­ate groups. Different citrate groups are linked via the three Ag(+) ions, yielding a three-dimensional network with rather irregular [AgO(4)] polyhedra.

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