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Bis(N,N-diisopropyl­butanaminium) bis­[di-μ-chlorido-bis­[dichlorido­cuprate(II)]]

In the title compound, (C(10)H(24)N)(2)[Cu(2)Cl(6)], N,N-diisopropyl­butanamine is protonated on the N atom. The Cu(II) atom in the centrosymmetric [Cu(2)Cl(6)](2−) anion has a distorted tetra­hedral geometry. In the crystal, the cations and anions are connected by N—H⋯Cl and C—H⋯Cl hydrogen bonds i...

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Detalles Bibliográficos
Autores principales: Dai, Jing, Xu, Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051450/
https://www.ncbi.nlm.nih.gov/pubmed/21522847
http://dx.doi.org/10.1107/S1600536810054280
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author Dai, Jing
Xu, Jie
author_facet Dai, Jing
Xu, Jie
author_sort Dai, Jing
collection PubMed
description In the title compound, (C(10)H(24)N)(2)[Cu(2)Cl(6)], N,N-diisopropyl­butanamine is protonated on the N atom. The Cu(II) atom in the centrosymmetric [Cu(2)Cl(6)](2−) anion has a distorted tetra­hedral geometry. In the crystal, the cations and anions are connected by N—H⋯Cl and C—H⋯Cl hydrogen bonds into layers parallel to (100).
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spelling pubmed-30514502011-04-26 Bis(N,N-diisopropyl­butanaminium) bis­[di-μ-chlorido-bis­[dichlorido­cuprate(II)]] Dai, Jing Xu, Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(10)H(24)N)(2)[Cu(2)Cl(6)], N,N-diisopropyl­butanamine is protonated on the N atom. The Cu(II) atom in the centrosymmetric [Cu(2)Cl(6)](2−) anion has a distorted tetra­hedral geometry. In the crystal, the cations and anions are connected by N—H⋯Cl and C—H⋯Cl hydrogen bonds into layers parallel to (100). International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051450/ /pubmed/21522847 http://dx.doi.org/10.1107/S1600536810054280 Text en © Dai and Xu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dai, Jing
Xu, Jie
Bis(N,N-diisopropyl­butanaminium) bis­[di-μ-chlorido-bis­[dichlorido­cuprate(II)]]
title Bis(N,N-diisopropyl­butanaminium) bis­[di-μ-chlorido-bis­[dichlorido­cuprate(II)]]
title_full Bis(N,N-diisopropyl­butanaminium) bis­[di-μ-chlorido-bis­[dichlorido­cuprate(II)]]
title_fullStr Bis(N,N-diisopropyl­butanaminium) bis­[di-μ-chlorido-bis­[dichlorido­cuprate(II)]]
title_full_unstemmed Bis(N,N-diisopropyl­butanaminium) bis­[di-μ-chlorido-bis­[dichlorido­cuprate(II)]]
title_short Bis(N,N-diisopropyl­butanaminium) bis­[di-μ-chlorido-bis­[dichlorido­cuprate(II)]]
title_sort bis(n,n-diisopropyl­butanaminium) bis­[di-μ-chlorido-bis­[dichlorido­cuprate(ii)]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051450/
https://www.ncbi.nlm.nih.gov/pubmed/21522847
http://dx.doi.org/10.1107/S1600536810054280
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