Hexaaqua­magnesium bis­{4-[(5-bromo-2-hy­droxy­benzyl­idene)amino]­benzene­sulfonate} dihydrate

In the title hydrated mol­ecular salt, [Mg(H(2)O)(6)](C(13)H(9)BrNO(4)S)(2)·2H(2)O, the Mg(2+) ion (site symmetry [Image: see text]) adopts a near regular MgO(6) octa­hedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5 (2)° and an intra­molecular O—H⋯N hy...

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Autor principal: Tai, Xi-Shi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051451/
https://www.ncbi.nlm.nih.gov/pubmed/21522820
http://dx.doi.org/10.1107/S1600536810053717
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author Tai, Xi-Shi
author_facet Tai, Xi-Shi
author_sort Tai, Xi-Shi
collection PubMed
description In the title hydrated mol­ecular salt, [Mg(H(2)O)(6)](C(13)H(9)BrNO(4)S)(2)·2H(2)O, the Mg(2+) ion (site symmetry [Image: see text]) adopts a near regular MgO(6) octa­hedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5 (2)° and an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal, the components are linked by O—H⋯O and O—H⋯Br hydrogen bonds.
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spelling pubmed-30514512011-04-26 Hexaaqua­magnesium bis­{4-[(5-bromo-2-hy­droxy­benzyl­idene)amino]­benzene­sulfonate} dihydrate Tai, Xi-Shi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title hydrated mol­ecular salt, [Mg(H(2)O)(6)](C(13)H(9)BrNO(4)S)(2)·2H(2)O, the Mg(2+) ion (site symmetry [Image: see text]) adopts a near regular MgO(6) octa­hedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5 (2)° and an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal, the components are linked by O—H⋯O and O—H⋯Br hydrogen bonds. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051451/ /pubmed/21522820 http://dx.doi.org/10.1107/S1600536810053717 Text en © Xi-Shi Tai 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tai, Xi-Shi
Hexaaqua­magnesium bis­{4-[(5-bromo-2-hy­droxy­benzyl­idene)amino]­benzene­sulfonate} dihydrate
title Hexaaqua­magnesium bis­{4-[(5-bromo-2-hy­droxy­benzyl­idene)amino]­benzene­sulfonate} dihydrate
title_full Hexaaqua­magnesium bis­{4-[(5-bromo-2-hy­droxy­benzyl­idene)amino]­benzene­sulfonate} dihydrate
title_fullStr Hexaaqua­magnesium bis­{4-[(5-bromo-2-hy­droxy­benzyl­idene)amino]­benzene­sulfonate} dihydrate
title_full_unstemmed Hexaaqua­magnesium bis­{4-[(5-bromo-2-hy­droxy­benzyl­idene)amino]­benzene­sulfonate} dihydrate
title_short Hexaaqua­magnesium bis­{4-[(5-bromo-2-hy­droxy­benzyl­idene)amino]­benzene­sulfonate} dihydrate
title_sort hexaaqua­magnesium bis­{4-[(5-bromo-2-hy­droxy­benzyl­idene)amino]­benzene­sulfonate} dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051451/
https://www.ncbi.nlm.nih.gov/pubmed/21522820
http://dx.doi.org/10.1107/S1600536810053717
work_keys_str_mv AT taixishi hexaaquamagnesiumbis45bromo2hydroxybenzylideneaminobenzenesulfonatedihydrate

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