(Methanol-κO)(methano­lato-κO)oxido[N-(2-oxidobenzyl­idene)phenyl­alaninato-κ(3) O,N,O′]vanadium(V)

In the title complex, [V(C(16)H(13)NO(3))(CH(3)O)O(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate ligand derived from the condensation of salicyl­aldehyde and l-phenyl­alanine, a vanadyl O atom, a methano­late O atom and a methanol O atom, forming a distorted octa­hedral coordination ge...

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Detalles Bibliográficos
Autores principales: Bian, Lin, Li, Lianzhi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051455/
https://www.ncbi.nlm.nih.gov/pubmed/21522922
http://dx.doi.org/10.1107/S1600536811003163
Descripción
Sumario:In the title complex, [V(C(16)H(13)NO(3))(CH(3)O)O(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate ligand derived from the condensation of salicyl­aldehyde and l-phenyl­alanine, a vanadyl O atom, a methano­late O atom and a methanol O atom, forming a distorted octa­hedral coordination geometry. In the crystal, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds result in a two-dimensional structure parallel to (001).

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