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(Methanol-κO)(methanolato-κO)oxido[N-(2-oxidobenzylidene)phenylalaninato-κ(3) O,N,O′]vanadium(V)
In the title complex, [V(C(16)H(13)NO(3))(CH(3)O)O(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate ligand derived from the condensation of salicylaldehyde and l-phenylalanine, a vanadyl O atom, a methanolate O atom and a methanol O atom, forming a distorted octahedral coordination ge...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051455/ https://www.ncbi.nlm.nih.gov/pubmed/21522922 http://dx.doi.org/10.1107/S1600536811003163 |
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author | Bian, Lin Li, Lianzhi |
author_facet | Bian, Lin Li, Lianzhi |
author_sort | Bian, Lin |
collection | PubMed |
description | In the title complex, [V(C(16)H(13)NO(3))(CH(3)O)O(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate ligand derived from the condensation of salicylaldehyde and l-phenylalanine, a vanadyl O atom, a methanolate O atom and a methanol O atom, forming a distorted octahedral coordination geometry. In the crystal, intermolecular O—H⋯O and C—H⋯O hydrogen bonds result in a two-dimensional structure parallel to (001). |
format | Text |
id | pubmed-3051455 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30514552011-04-26 (Methanol-κO)(methanolato-κO)oxido[N-(2-oxidobenzylidene)phenylalaninato-κ(3) O,N,O′]vanadium(V) Bian, Lin Li, Lianzhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [V(C(16)H(13)NO(3))(CH(3)O)O(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate ligand derived from the condensation of salicylaldehyde and l-phenylalanine, a vanadyl O atom, a methanolate O atom and a methanol O atom, forming a distorted octahedral coordination geometry. In the crystal, intermolecular O—H⋯O and C—H⋯O hydrogen bonds result in a two-dimensional structure parallel to (001). International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051455/ /pubmed/21522922 http://dx.doi.org/10.1107/S1600536811003163 Text en © Bian and Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bian, Lin Li, Lianzhi (Methanol-κO)(methanolato-κO)oxido[N-(2-oxidobenzylidene)phenylalaninato-κ(3) O,N,O′]vanadium(V) |
title | (Methanol-κO)(methanolato-κO)oxido[N-(2-oxidobenzylidene)phenylalaninato-κ(3)
O,N,O′]vanadium(V) |
title_full | (Methanol-κO)(methanolato-κO)oxido[N-(2-oxidobenzylidene)phenylalaninato-κ(3)
O,N,O′]vanadium(V) |
title_fullStr | (Methanol-κO)(methanolato-κO)oxido[N-(2-oxidobenzylidene)phenylalaninato-κ(3)
O,N,O′]vanadium(V) |
title_full_unstemmed | (Methanol-κO)(methanolato-κO)oxido[N-(2-oxidobenzylidene)phenylalaninato-κ(3)
O,N,O′]vanadium(V) |
title_short | (Methanol-κO)(methanolato-κO)oxido[N-(2-oxidobenzylidene)phenylalaninato-κ(3)
O,N,O′]vanadium(V) |
title_sort | (methanol-κo)(methanolato-κo)oxido[n-(2-oxidobenzylidene)phenylalaninato-κ(3)
o,n,o′]vanadium(v) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051455/ https://www.ncbi.nlm.nih.gov/pubmed/21522922 http://dx.doi.org/10.1107/S1600536811003163 |
work_keys_str_mv | AT bianlin methanolkomethanolatokooxidon2oxidobenzylidenephenylalaninatok3onovanadiumv AT lilianzhi methanolkomethanolatokooxidon2oxidobenzylidenephenylalaninatok3onovanadiumv |