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[μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-(meth­oxy­phen­yl)arsane-3κAs]-triangulo-triruthenium(0) chloro­form monosolvate

The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)AsO(3))(C(26)H(24)P(2))(CO)(9)]·CHCl(3), consists of one mol­ecule of the triangulo-triruthenium complex and one chloro­form solvent mol­ecule. The bis(diphenyl­phosphan­yl)ethane ligand bridges an Ru—Ru bond and the...

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Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Sirat, Siti Syaida, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051462/
https://www.ncbi.nlm.nih.gov/pubmed/21522851
http://dx.doi.org/10.1107/S160053681100047X
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author Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Sirat, Siti Syaida
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Sirat, Siti Syaida
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Shawkataly, Omar bin
collection PubMed
description The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)AsO(3))(C(26)H(24)P(2))(CO)(9)]·CHCl(3), consists of one mol­ecule of the triangulo-triruthenium complex and one chloro­form solvent mol­ecule. The bis(diphenyl­phosphan­yl)ethane ligand bridges an Ru—Ru bond and the monodentate arsane ligand bonds to the third Ru atom. Both the arsane and phosphine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three arsane-substituted benzene rings make dihedral angles of 52.72 (19), 63.03 (19) and 88.19 (19)° with each other. The dihedral angles between the two benzene rings are 85.8 (2) and 89.2 (2)° for the two diphenyl­phosphanyl groups. In the crystal, mol­ecules are linked together into a three-dimensional network via inter­molecular C—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯π inter­actions further stabilize the crystal structure.
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spelling pubmed-30514622011-04-26 [μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-(meth­oxy­phen­yl)arsane-3κAs]-triangulo-triruthenium(0) chloro­form monosolvate Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)AsO(3))(C(26)H(24)P(2))(CO)(9)]·CHCl(3), consists of one mol­ecule of the triangulo-triruthenium complex and one chloro­form solvent mol­ecule. The bis(diphenyl­phosphan­yl)ethane ligand bridges an Ru—Ru bond and the monodentate arsane ligand bonds to the third Ru atom. Both the arsane and phosphine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three arsane-substituted benzene rings make dihedral angles of 52.72 (19), 63.03 (19) and 88.19 (19)° with each other. The dihedral angles between the two benzene rings are 85.8 (2) and 89.2 (2)° for the two diphenyl­phosphanyl groups. In the crystal, mol­ecules are linked together into a three-dimensional network via inter­molecular C—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯π inter­actions further stabilize the crystal structure. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051462/ /pubmed/21522851 http://dx.doi.org/10.1107/S160053681100047X Text en © Shawkataly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Sirat, Siti Syaida
Yeap, Chin Sing
Fun, Hoong-Kun
[μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-(meth­oxy­phen­yl)arsane-3κAs]-triangulo-triruthenium(0) chloro­form monosolvate
title [μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-(meth­oxy­phen­yl)arsane-3κAs]-triangulo-triruthenium(0) chloro­form monosolvate
title_full [μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-(meth­oxy­phen­yl)arsane-3κAs]-triangulo-triruthenium(0) chloro­form monosolvate
title_fullStr [μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-(meth­oxy­phen­yl)arsane-3κAs]-triangulo-triruthenium(0) chloro­form monosolvate
title_full_unstemmed [μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-(meth­oxy­phen­yl)arsane-3κAs]-triangulo-triruthenium(0) chloro­form monosolvate
title_short [μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(4-(meth­oxy­phen­yl)arsane-3κAs]-triangulo-triruthenium(0) chloro­form monosolvate
title_sort [μ-bis(diphenyl­phosphan­yl)ethane-1:2κ(2) p:p′]nona­carbonyl-1κ(3) c,2κ(3) c,3κ(3) c-[tris­(4-(meth­oxy­phen­yl)arsane-3κas]-triangulo-triruthenium(0) chloro­form monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051462/
https://www.ncbi.nlm.nih.gov/pubmed/21522851
http://dx.doi.org/10.1107/S160053681100047X
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