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[μ-Bis(diphenylphosphanyl)ethane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(4-(methoxyphenyl)arsane-3κAs]-triangulo-triruthenium(0) chloroform monosolvate
The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)AsO(3))(C(26)H(24)P(2))(CO)(9)]·CHCl(3), consists of one molecule of the triangulo-triruthenium complex and one chloroform solvent molecule. The bis(diphenylphosphanyl)ethane ligand bridges an Ru—Ru bond and the...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051462/ https://www.ncbi.nlm.nih.gov/pubmed/21522851 http://dx.doi.org/10.1107/S160053681100047X |
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author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun |
author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun |
author_sort | Shawkataly, Omar bin |
collection | PubMed |
description | The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)AsO(3))(C(26)H(24)P(2))(CO)(9)]·CHCl(3), consists of one molecule of the triangulo-triruthenium complex and one chloroform solvent molecule. The bis(diphenylphosphanyl)ethane ligand bridges an Ru—Ru bond and the monodentate arsane ligand bonds to the third Ru atom. Both the arsane and phosphine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three arsane-substituted benzene rings make dihedral angles of 52.72 (19), 63.03 (19) and 88.19 (19)° with each other. The dihedral angles between the two benzene rings are 85.8 (2) and 89.2 (2)° for the two diphenylphosphanyl groups. In the crystal, molecules are linked together into a three-dimensional network via intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure. |
format | Text |
id | pubmed-3051462 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30514622011-04-26 [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(4-(methoxyphenyl)arsane-3κAs]-triangulo-triruthenium(0) chloroform monosolvate Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)AsO(3))(C(26)H(24)P(2))(CO)(9)]·CHCl(3), consists of one molecule of the triangulo-triruthenium complex and one chloroform solvent molecule. The bis(diphenylphosphanyl)ethane ligand bridges an Ru—Ru bond and the monodentate arsane ligand bonds to the third Ru atom. Both the arsane and phosphine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three arsane-substituted benzene rings make dihedral angles of 52.72 (19), 63.03 (19) and 88.19 (19)° with each other. The dihedral angles between the two benzene rings are 85.8 (2) and 89.2 (2)° for the two diphenylphosphanyl groups. In the crystal, molecules are linked together into a three-dimensional network via intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051462/ /pubmed/21522851 http://dx.doi.org/10.1107/S160053681100047X Text en © Shawkataly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(4-(methoxyphenyl)arsane-3κAs]-triangulo-triruthenium(0) chloroform monosolvate |
title | [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-(methoxyphenyl)arsane-3κAs]-triangulo-triruthenium(0) chloroform monosolvate |
title_full | [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-(methoxyphenyl)arsane-3κAs]-triangulo-triruthenium(0) chloroform monosolvate |
title_fullStr | [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-(methoxyphenyl)arsane-3κAs]-triangulo-triruthenium(0) chloroform monosolvate |
title_full_unstemmed | [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-(methoxyphenyl)arsane-3κAs]-triangulo-triruthenium(0) chloroform monosolvate |
title_short | [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(4-(methoxyphenyl)arsane-3κAs]-triangulo-triruthenium(0) chloroform monosolvate |
title_sort | [μ-bis(diphenylphosphanyl)ethane-1:2κ(2)
p:p′]nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-[tris(4-(methoxyphenyl)arsane-3κas]-triangulo-triruthenium(0) chloroform monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051462/ https://www.ncbi.nlm.nih.gov/pubmed/21522851 http://dx.doi.org/10.1107/S160053681100047X |
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