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(2,2′-Bipyridine)(pyridine-2,6-dicarboxylato)oxidovanadium(IV) ethanol monosolvate
In the title compound, [V(C(7)H(3)NO(4))O(C(10)H(8)N(2))]·C(2)H(5)OH, the V(IV) atom exhibits a distorted octahedral coordination environment formed by two pyridyl N atoms of 2,2′-bipyridine (bpy), the vanadyl O atom, and two carboxylate O atoms and one pyridyl N atom of the tridentate pyridine-2,...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051467/ https://www.ncbi.nlm.nih.gov/pubmed/21522903 http://dx.doi.org/10.1107/S1600536811002376 |
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author | Aghabozorg, Hossein Tavakoli, Elnaz Mirzaei, Masoud |
author_facet | Aghabozorg, Hossein Tavakoli, Elnaz Mirzaei, Masoud |
author_sort | Aghabozorg, Hossein |
collection | PubMed |
description | In the title compound, [V(C(7)H(3)NO(4))O(C(10)H(8)N(2))]·C(2)H(5)OH, the V(IV) atom exhibits a distorted octahedral coordination environment formed by two pyridyl N atoms of 2,2′-bipyridine (bpy), the vanadyl O atom, and two carboxylate O atoms and one pyridyl N atom of the tridentate pyridine-2,6-dicarboxylate (pydc(2−)) ligand. The pyridyl N atom of the pydc(2−) anion and one pyridyl N atom of bpy occupy the axial positions. O—H⋯O hydrogen bonds involving the ethanol solvent molecule as donor and a carboxylate O atom as acceptor atoms, as well as C—H⋯O hydrogen bonds, together with π–π stacking interactions between adjacent aromatic rings (average centroid–centroid distance = 3.577 Å), seem to be effective in the stabilization of the crystal packing, resulting in the formation of a three-dimensional structure. |
format | Text |
id | pubmed-3051467 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30514672011-04-26 (2,2′-Bipyridine)(pyridine-2,6-dicarboxylato)oxidovanadium(IV) ethanol monosolvate Aghabozorg, Hossein Tavakoli, Elnaz Mirzaei, Masoud Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [V(C(7)H(3)NO(4))O(C(10)H(8)N(2))]·C(2)H(5)OH, the V(IV) atom exhibits a distorted octahedral coordination environment formed by two pyridyl N atoms of 2,2′-bipyridine (bpy), the vanadyl O atom, and two carboxylate O atoms and one pyridyl N atom of the tridentate pyridine-2,6-dicarboxylate (pydc(2−)) ligand. The pyridyl N atom of the pydc(2−) anion and one pyridyl N atom of bpy occupy the axial positions. O—H⋯O hydrogen bonds involving the ethanol solvent molecule as donor and a carboxylate O atom as acceptor atoms, as well as C—H⋯O hydrogen bonds, together with π–π stacking interactions between adjacent aromatic rings (average centroid–centroid distance = 3.577 Å), seem to be effective in the stabilization of the crystal packing, resulting in the formation of a three-dimensional structure. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051467/ /pubmed/21522903 http://dx.doi.org/10.1107/S1600536811002376 Text en © Aghabozorg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Aghabozorg, Hossein Tavakoli, Elnaz Mirzaei, Masoud (2,2′-Bipyridine)(pyridine-2,6-dicarboxylato)oxidovanadium(IV) ethanol monosolvate |
title | (2,2′-Bipyridine)(pyridine-2,6-dicarboxylato)oxidovanadium(IV) ethanol monosolvate |
title_full | (2,2′-Bipyridine)(pyridine-2,6-dicarboxylato)oxidovanadium(IV) ethanol monosolvate |
title_fullStr | (2,2′-Bipyridine)(pyridine-2,6-dicarboxylato)oxidovanadium(IV) ethanol monosolvate |
title_full_unstemmed | (2,2′-Bipyridine)(pyridine-2,6-dicarboxylato)oxidovanadium(IV) ethanol monosolvate |
title_short | (2,2′-Bipyridine)(pyridine-2,6-dicarboxylato)oxidovanadium(IV) ethanol monosolvate |
title_sort | (2,2′-bipyridine)(pyridine-2,6-dicarboxylato)oxidovanadium(iv) ethanol monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051467/ https://www.ncbi.nlm.nih.gov/pubmed/21522903 http://dx.doi.org/10.1107/S1600536811002376 |
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