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(2,2′-Bipyridine)(pyridine-2,6-dicarboxyl­ato)oxidovanadium(IV) ethanol monosolvate

In the title compound, [V(C(7)H(3)NO(4))O(C(10)H(8)N(2))]·C(2)H(5)OH, the V(IV) atom exhibits a distorted octa­hedral coordination environment formed by two pyridyl N atoms of 2,2′-bipyridine (bpy), the vanadyl O atom, and two carboxyl­ate O atoms and one pyridyl N atom of the tridentate pyridine-2,...

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Autores principales: Aghabozorg, Hossein, Tavakoli, Elnaz, Mirzaei, Masoud
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051467/
https://www.ncbi.nlm.nih.gov/pubmed/21522903
http://dx.doi.org/10.1107/S1600536811002376
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author Aghabozorg, Hossein
Tavakoli, Elnaz
Mirzaei, Masoud
author_facet Aghabozorg, Hossein
Tavakoli, Elnaz
Mirzaei, Masoud
author_sort Aghabozorg, Hossein
collection PubMed
description In the title compound, [V(C(7)H(3)NO(4))O(C(10)H(8)N(2))]·C(2)H(5)OH, the V(IV) atom exhibits a distorted octa­hedral coordination environment formed by two pyridyl N atoms of 2,2′-bipyridine (bpy), the vanadyl O atom, and two carboxyl­ate O atoms and one pyridyl N atom of the tridentate pyridine-2,6-dicarboxyl­ate (pydc(2−)) ligand. The pyridyl N atom of the pydc(2−) anion and one pyridyl N atom of bpy occupy the axial positions. O—H⋯O hydrogen bonds involving the ethanol solvent mol­ecule as donor and a carboxyl­ate O atom as acceptor atoms, as well as C—H⋯O hydrogen bonds, together with π–π stacking inter­actions between adjacent aromatic rings (average centroid–centroid distance = 3.577 Å), seem to be effective in the stabilization of the crystal packing, resulting in the formation of a three-dimensional structure.
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spelling pubmed-30514672011-04-26 (2,2′-Bipyridine)(pyridine-2,6-dicarboxyl­ato)oxidovanadium(IV) ethanol monosolvate Aghabozorg, Hossein Tavakoli, Elnaz Mirzaei, Masoud Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [V(C(7)H(3)NO(4))O(C(10)H(8)N(2))]·C(2)H(5)OH, the V(IV) atom exhibits a distorted octa­hedral coordination environment formed by two pyridyl N atoms of 2,2′-bipyridine (bpy), the vanadyl O atom, and two carboxyl­ate O atoms and one pyridyl N atom of the tridentate pyridine-2,6-dicarboxyl­ate (pydc(2−)) ligand. The pyridyl N atom of the pydc(2−) anion and one pyridyl N atom of bpy occupy the axial positions. O—H⋯O hydrogen bonds involving the ethanol solvent mol­ecule as donor and a carboxyl­ate O atom as acceptor atoms, as well as C—H⋯O hydrogen bonds, together with π–π stacking inter­actions between adjacent aromatic rings (average centroid–centroid distance = 3.577 Å), seem to be effective in the stabilization of the crystal packing, resulting in the formation of a three-dimensional structure. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051467/ /pubmed/21522903 http://dx.doi.org/10.1107/S1600536811002376 Text en © Aghabozorg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Aghabozorg, Hossein
Tavakoli, Elnaz
Mirzaei, Masoud
(2,2′-Bipyridine)(pyridine-2,6-dicarboxyl­ato)oxidovanadium(IV) ethanol monosolvate
title (2,2′-Bipyridine)(pyridine-2,6-dicarboxyl­ato)oxidovanadium(IV) ethanol monosolvate
title_full (2,2′-Bipyridine)(pyridine-2,6-dicarboxyl­ato)oxidovanadium(IV) ethanol monosolvate
title_fullStr (2,2′-Bipyridine)(pyridine-2,6-dicarboxyl­ato)oxidovanadium(IV) ethanol monosolvate
title_full_unstemmed (2,2′-Bipyridine)(pyridine-2,6-dicarboxyl­ato)oxidovanadium(IV) ethanol monosolvate
title_short (2,2′-Bipyridine)(pyridine-2,6-dicarboxyl­ato)oxidovanadium(IV) ethanol monosolvate
title_sort (2,2′-bipyridine)(pyridine-2,6-dicarboxyl­ato)oxidovanadium(iv) ethanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051467/
https://www.ncbi.nlm.nih.gov/pubmed/21522903
http://dx.doi.org/10.1107/S1600536811002376
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