Di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N-bis­({2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}(thio­cyanato-κN)cadmium)

In the title complex, [Cd(2)(NCS)(4)(C(13)H(19)N(3)O)(2)], the two Cd(II) ions are bridged by a pair of thio­cyanate N:S-bridging ligands around an inversion center. One terminal thio­cyanate N atom and one N,N′,N′′-tridentate Schiff base ligand complete a distorted CdN(5)S octa­hedral geometry abou...

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Detalles Bibliográficos
Autores principales: Suleiman Gwaram, Nura, Ikmal Hisham, Nurul Azimah, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051469/
https://www.ncbi.nlm.nih.gov/pubmed/21522905
http://dx.doi.org/10.1107/S1600536811002480
Descripción
Sumario:In the title complex, [Cd(2)(NCS)(4)(C(13)H(19)N(3)O)(2)], the two Cd(II) ions are bridged by a pair of thio­cyanate N:S-bridging ligands around an inversion center. One terminal thio­cyanate N atom and one N,N′,N′′-tridentate Schiff base ligand complete a distorted CdN(5)S octa­hedral geometry about each Cd(II) atom. In the crystal, the Schiff base aromatic rings of adjacent mol­ecules are arranged above each other into infinite chains along the a axis with alternate centroid–centroid separations of 3.5299 (13) and 3.7857 (13) Å.

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