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Di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis({2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3) N,N′,N′′}(thiocyanato-κN)cadmium)
In the title complex, [Cd(2)(NCS)(4)(C(13)H(19)N(3)O)(2)], the two Cd(II) ions are bridged by a pair of thiocyanate N:S-bridging ligands around an inversion center. One terminal thiocyanate N atom and one N,N′,N′′-tridentate Schiff base ligand complete a distorted CdN(5)S octahedral geometry abou...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051469/ https://www.ncbi.nlm.nih.gov/pubmed/21522905 http://dx.doi.org/10.1107/S1600536811002480 |
| _version_ | 1782199486336991232 |
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| author | Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah |
| author_facet | Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah |
| author_sort | Suleiman Gwaram, Nura |
| collection | PubMed |
| description | In the title complex, [Cd(2)(NCS)(4)(C(13)H(19)N(3)O)(2)], the two Cd(II) ions are bridged by a pair of thiocyanate N:S-bridging ligands around an inversion center. One terminal thiocyanate N atom and one N,N′,N′′-tridentate Schiff base ligand complete a distorted CdN(5)S octahedral geometry about each Cd(II) atom. In the crystal, the Schiff base aromatic rings of adjacent molecules are arranged above each other into infinite chains along the a axis with alternate centroid–centroid separations of 3.5299 (13) and 3.7857 (13) Å. |
| format | Text |
| id | pubmed-3051469 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30514692011-04-26 Di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis({2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3) N,N′,N′′}(thiocyanato-κN)cadmium) Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(2)(NCS)(4)(C(13)H(19)N(3)O)(2)], the two Cd(II) ions are bridged by a pair of thiocyanate N:S-bridging ligands around an inversion center. One terminal thiocyanate N atom and one N,N′,N′′-tridentate Schiff base ligand complete a distorted CdN(5)S octahedral geometry about each Cd(II) atom. In the crystal, the Schiff base aromatic rings of adjacent molecules are arranged above each other into infinite chains along the a axis with alternate centroid–centroid separations of 3.5299 (13) and 3.7857 (13) Å. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051469/ /pubmed/21522905 http://dx.doi.org/10.1107/S1600536811002480 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah Di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis({2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3) N,N′,N′′}(thiocyanato-κN)cadmium) |
| title | Di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis({2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}(thiocyanato-κN)cadmium) |
| title_full | Di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis({2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}(thiocyanato-κN)cadmium) |
| title_fullStr | Di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis({2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}(thiocyanato-κN)cadmium) |
| title_full_unstemmed | Di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis({2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}(thiocyanato-κN)cadmium) |
| title_short | Di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis({2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}(thiocyanato-κN)cadmium) |
| title_sort | di-μ-thiocyanato-κ(2)
n:s;κ(2)
s:n-bis({2-morpholino-n-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
n,n′,n′′}(thiocyanato-κn)cadmium) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051469/ https://www.ncbi.nlm.nih.gov/pubmed/21522905 http://dx.doi.org/10.1107/S1600536811002480 |
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