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[μ-1,2-Bis(diphenyl­phosphan­yl)-1,2-diethyl­hydrazine-κ(2) P:P′]bis­[chlorido­gold(I)] tetra­hydro­furan disolvate

The title compound, [Au(2)Cl(2)(C(28)H(30)N(2)P(2))]·2C(4)H(8)O, was synthesized from a bidentate phosphine ligand complexed to two linear gold(I) chloride moieties. The Au(I) atom is in an almost linear coordination with a P—Au—Cl angle of 179.22 (4)°. The complex molecules reside on a twofold rota...

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Detalles Bibliográficos
Autores principales: Kriel, Frederik H., Fernandes, Manuel A., Coates, Judy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051471/
https://www.ncbi.nlm.nih.gov/pubmed/21522837
http://dx.doi.org/10.1107/S1600536811000109
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author Kriel, Frederik H.
Fernandes, Manuel A.
Coates, Judy
author_facet Kriel, Frederik H.
Fernandes, Manuel A.
Coates, Judy
author_sort Kriel, Frederik H.
collection PubMed
description The title compound, [Au(2)Cl(2)(C(28)H(30)N(2)P(2))]·2C(4)H(8)O, was synthesized from a bidentate phosphine ligand complexed to two linear gold(I) chloride moieties. The Au(I) atom is in an almost linear coordination with a P—Au—Cl angle of 179.22 (4)°. The complex molecules reside on a twofold rotation axis.
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spelling pubmed-30514712011-04-26 [μ-1,2-Bis(diphenyl­phosphan­yl)-1,2-diethyl­hydrazine-κ(2) P:P′]bis­[chlorido­gold(I)] tetra­hydro­furan disolvate Kriel, Frederik H. Fernandes, Manuel A. Coates, Judy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Au(2)Cl(2)(C(28)H(30)N(2)P(2))]·2C(4)H(8)O, was synthesized from a bidentate phosphine ligand complexed to two linear gold(I) chloride moieties. The Au(I) atom is in an almost linear coordination with a P—Au—Cl angle of 179.22 (4)°. The complex molecules reside on a twofold rotation axis. International Union of Crystallography 2011-01-12 /pmc/articles/PMC3051471/ /pubmed/21522837 http://dx.doi.org/10.1107/S1600536811000109 Text en © Kriel et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kriel, Frederik H.
Fernandes, Manuel A.
Coates, Judy
[μ-1,2-Bis(diphenyl­phosphan­yl)-1,2-diethyl­hydrazine-κ(2) P:P′]bis­[chlorido­gold(I)] tetra­hydro­furan disolvate
title [μ-1,2-Bis(diphenyl­phosphan­yl)-1,2-diethyl­hydrazine-κ(2) P:P′]bis­[chlorido­gold(I)] tetra­hydro­furan disolvate
title_full [μ-1,2-Bis(diphenyl­phosphan­yl)-1,2-diethyl­hydrazine-κ(2) P:P′]bis­[chlorido­gold(I)] tetra­hydro­furan disolvate
title_fullStr [μ-1,2-Bis(diphenyl­phosphan­yl)-1,2-diethyl­hydrazine-κ(2) P:P′]bis­[chlorido­gold(I)] tetra­hydro­furan disolvate
title_full_unstemmed [μ-1,2-Bis(diphenyl­phosphan­yl)-1,2-diethyl­hydrazine-κ(2) P:P′]bis­[chlorido­gold(I)] tetra­hydro­furan disolvate
title_short [μ-1,2-Bis(diphenyl­phosphan­yl)-1,2-diethyl­hydrazine-κ(2) P:P′]bis­[chlorido­gold(I)] tetra­hydro­furan disolvate
title_sort [μ-1,2-bis(diphenyl­phosphan­yl)-1,2-diethyl­hydrazine-κ(2) p:p′]bis­[chlorido­gold(i)] tetra­hydro­furan disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051471/
https://www.ncbi.nlm.nih.gov/pubmed/21522837
http://dx.doi.org/10.1107/S1600536811000109
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