Bis(2-{5-[(2-carb­oxy­phen­yl)sulfanylmeth­yl]-2,4-dimethyl­benzyl­sulfan­yl}benzoato-κ(2) O,O′)bis­(pyridine-κN)iron(II)

The title compound, [Fe(C(24)H(21)O(4)S(2))(2)(C(5)H(5)N)(2)], has 2 symmetry. The Fe(II) cation is located on a twofold rotation axis and is O,O′-chelated by two 2-{5-[(2-carb­oxy­phen­yl)sulfanylmeth­yl]-2,4-dimethyl­benzyl­sulfan­yl}benzoate anions and further coordinated by two pyridine ligands...

Descripción completa

Detalles Bibliográficos
Autores principales: Xu, Yu-Min, Hu, Tuo-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051472/
https://www.ncbi.nlm.nih.gov/pubmed/21522840
http://dx.doi.org/10.1107/S1600536810054619
Descripción
Sumario:The title compound, [Fe(C(24)H(21)O(4)S(2))(2)(C(5)H(5)N)(2)], has 2 symmetry. The Fe(II) cation is located on a twofold rotation axis and is O,O′-chelated by two 2-{5-[(2-carb­oxy­phen­yl)sulfanylmeth­yl]-2,4-dimethyl­benzyl­sulfan­yl}benzoate anions and further coordinated by two pyridine ligands in a distorted octa­hedral geometry. In the anion, the terminal benzene rings are oriented at dihedral angles of 63.81 (14) and 84.50 (14)° with respect to the central benzene ring. Inter­molecular O—H⋯O and C—H⋯O hydrogen bonding is present in the crystal structure.

Ejemplares similares